Reduced graphene oxide-CuFe2O4 nanocomposite: A highly sensitive room temperature NH3 gas sensor

被引:120
作者
Achary, L. Satish K. [1 ]
Kumar, Aniket [1 ]
Barik, Bapun [1 ]
Nayak, Pratap S. [1 ]
Tripathy, Nilakantha [2 ]
Kar, Jyoti P. [2 ]
Dash, Priyabrat [1 ]
机构
[1] Natl Inst Technol, Dept Chem, Rourkela 769008, Odisha, India
[2] Natl Inst Technol, Dept Phys, Rourkela 769008, Odisha, India
关键词
Reduced graphene Oxide(rGO); Spinel CuFe2O4; NH3; gas; Gas sensing; Nanocomposite; SENSING PROPERTIES; OXIDE RGO; DIELECTRIC-PROPERTIES; SPINEL FERRITE; ZINC FERRITE; AMMONIA; NANOPARTICLES; NANOFIBERS; COMPOSITE; POLYANILINE;
D O I
10.1016/j.snb.2018.05.093
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Sensitive and selective detection of NH3 at room temperature is required for proper environmental monitoring and also to avoid any health hazards in the industrial areas. Towards this objective, a low-cost, one-step and combustion route mediated reduced graphene oxide (rGO)-CuFe2O4 nanocomposite was exploited as a high-performance NH3 gas sensor by combining the excellent electrical properties of rGO and sensing capabilities of CuFe2O4. This nanocomposite was characterized using Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Transmission electron microscopy (TEM) and N-2 adsorption-desorption analysis. The TEM images demonstrate the uniform distribution of the nanoparticles on the rGO surface and high-resolution transmission electron microscopy (HRTEM) confirms an average particle size of 15-20 nm. The designed sensor can detect NH3 at low concentrations up to 5 ppm at room temperature. Besides high sensing ability, the designed nanocomposite showed good recyclability suggesting its potential applications for the detection of environmentally toxic gases. The enhanced sensing behavior can be attributed to the synergistic behavior between individual rGO and CuFe2O4 component.
引用
收藏
页码:100 / 109
页数:10
相关论文
共 52 条
[1]   Highly sensitive, room temperature gas sensor based on polyaniline-multiwalled carbon nanotubes (PANI/MWCNTs) nanocomposite for trace-level ammonia detection [J].
Abdulla, Sukhananazerin ;
Mathew, Thalakkotur Lazar ;
Pullithadathil, Biji .
SENSORS AND ACTUATORS B-CHEMICAL, 2015, 221 :1523-1534
[2]  
[Anonymous], 2017, SCI REP UK
[3]   Toxic gas removal - metal-organic frameworks for the capture and degradation of toxic gases and vapours [J].
Barea, Elisa ;
Montoro, Carmen ;
Navarro, Jorge A. R. .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :5419-5430
[4]   Copper doped manganese ferrites nanoparticles anchored on graphene nano-sheets for high performance energy storage applications [J].
Bashir, Bushra ;
Shaheen, Wajeeha ;
Asghar, Muhammad ;
Warsi, Muhammad Farooq ;
Khan, Muhammad Azhar ;
Haider, Sajjad ;
Shakir, Imran ;
Shahid, Muhammad .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 695 :881-887
[5]   Characteristics of ZnO nanorods-based ammonia gas sensors with a cross-linked configuration [J].
Chen, Tai-You ;
Chen, Huey-Ing ;
Hsu, Chi-Shiang ;
Huang, Chien-Chang ;
Wu, Jian-Sheng ;
Chou, Po-Cheng ;
Liu, Wen-Chau .
SENSORS AND ACTUATORS B-CHEMICAL, 2015, 221 :491-498
[6]   Morphologically Robust NiFe2O4 Nanofibers as High Capacity Li-Ion Battery Anode Material [J].
Cherian, Christie Thomas ;
Sundaramurthy, Jayaraman ;
Reddy, M. V. ;
Kumar, Palanisamy Suresh ;
Mani, Kalaivani ;
Pliszka, Damian ;
Sow, Chorng Haur ;
Ramakrishna, Seeram ;
Chowdari, B. V. R. .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (20) :9957-9963
[7]   Ethanol gas sensor based on CoFe2O4 nano-crystallines prepared by hydrothermal method [J].
Chu Xiangfeng ;
Jiang Dongli ;
Yu, Guo ;
Zheng Chenmou .
SENSORS AND ACTUATORS B-CHEMICAL, 2006, 120 (01) :177-181
[8]   Percolation effect of reduced graphene oxide (rGO) on ammonia sensing of rGO-SnO2 composite based sensor [J].
Feng, Qiuxia ;
Li, Xiaogan ;
Wang, Jing .
SENSORS AND ACTUATORS B-CHEMICAL, 2017, 243 :1115-1126
[9]   Reduced graphene oxide (rGO) encapsulated Co3O4 composite nanofibers for highly selective ammonia sensors [J].
Feng, Qiuxia ;
Li, Xiaogan ;
Wang, Jing ;
Gaskov, Alexander M. .
SENSORS AND ACTUATORS B-CHEMICAL, 2016, 222 :864-870
[10]   Gas sensing properties of magnesium ferrite prepared by co-precipitation method [J].
Hankare, P. P. ;
Jadhav, S. D. ;
Sankpal, U. B. ;
Patil, R. P. ;
Sasikala, R. ;
Mulla, I. S. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 488 (01) :270-272