Photoacid-mediated ring opening polymerization driven by visible light

被引:180
作者
Fu, Changkui
Xu, Jiangtao [1 ]
Boyer, Cyrille [1 ]
机构
[1] UNSW Australia, CAMD, Sydney, NSW 2052, Australia
关键词
LIVING RADICAL POLYMERIZATION; REDOX CONTROL; CATIONIC-POLYMERIZATION; CATALYSTS; WAVELENGTHS; PORPHYRINS; COPOLYMERS;
D O I
10.1039/c6cc03084j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel methodology of visible light regulated ring opening polymerization in the presence of reversible merocyanine-based photoacid was reported for the first time. In combination with a photoinduced radical polymerization technique, a dual wavelength light controlled orthogonal polymerization system was investigated to switch the polymerization between two different monomers and for the preparation of block and graft copolymers in one pot.
引用
收藏
页码:7126 / 7129
页数:4
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