Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction

被引：6

作者：

Bulygina, Ludmila A. ^{[1
]}

Khrushcheva, Natalya S. ^{[1
]}

Lyssenko, Konstantin A. ^{[2
,3
]}

Peregudov, Alexander S. ^{[1
]}

机构：

[1] Russian Acad Sci, A N Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[2] M V Lomonosov Moscow State Univ, Dept Chem, Moscow 119991, Russia

[3] Plekhanov Russian Univ Econ, Moscow 117997, Russia

来源：

MENDELEEV COMMUNICATIONS | 2022年 / 32卷 / 03期

关键词：

unsymmetrical pincer complexes; palladium complexes; ferrocene; bicyclic ligand precursor; LIGANDS; TERDENTATE;

D O I：

10.1016/j.mencom.2022.05.012

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New bicyclic unsymmetrical CNN palladium 5,6-membered pincer complex was synthesized from 3-ferrocenylmethyl-8dimethylamino-3-azabicyclo[3.2.1]octane by its direct cyclopalladation with Li(2)PdCl(4 )or Na2PdCl4 and sodium acetate in MeOH. The obtained complex exhibited high catalytic activity in the Suzuki cross-coupling between aryl bromides and phenylboronic acid.

引用

页码：331 / 333

页数：3

共 3 条

[1] 5,6-Membered CNN palladium pincer complexes of 3-benzyl-8-dimethylamino-3-azabicyclo[3.2.1]octane and 3-benzyl-9-dimethylamino-3-azabicyclo[3.3.1]nonane
Bulygina, Ludmila A.
Khrushcheva, Natalya S.
Lyssenko, Konstantin A.
Peregudov, Aleksander S.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2019, 887 : 64 - 70
[2] Unsymmetrical pincer CNN palladium complex of 7-ferrocenylmethyl-3-methyl-3,7-diazabicyclo[3.3.1] nonane
Bulygina, Ludmila A.
Kagramanov, Nikolay D.
Khrushcheva, Natalya S.
Lyssenko, Konstantin A.
Peregudov, Aleksander S.
Sokolov, Viacheslav I.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 846 : 169 - 175
[3] Synthesis, photophysical properties and catalytic activity of K3-SCS pincer palladium (II) complex of N,N′-di-tert-butylbenzene-1,3-dicarbothioamide supported by DFT analysis
Das, Debasish
Kannan, S.
Kumar, Mukesh
Sadhu, Biswajit
Kumbhare, Liladhar B.
INORGANICA CHIMICA ACTA, 2022, 531

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