Bis[μ-(E)-N′-(4-oxido-4-phenylbut-3-en-2-ylidene)benzohydrazidato]bis[pyridinecopper(II)]

被引:2
作者
Hatefi, Mehdi [1 ]
Sheikhshoaie, Iran [1 ]
Moghadam, Majid [2 ]
Mirkhani, Valiollah [2 ]
Kia, Reza [3 ,4 ]
机构
[1] Shahid Bahonar Univ, Dept Chem, Kerman, Iran
[2] Univ Isfahan, Dept Chem, Esfahan 8174673441, Iran
[3] Islamic Azad Univ, Dept Chem, Sci & Res Branch, Tehran, Iran
[4] Islamic Azad Univ, Xray Crystallog Lab, Plasma Phys Res Ctr, Sci & Res Branch, Tehran, Iran
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
D O I
10.1107/S1600536810019902
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the crystal structure of the title centrosymmetric dimer, [Cu 2(C17H14N2O2) 2(C5H5N)2], the CuII atom has an almost perfect square-pyramidal geometry. The CuII ion is coordin-ated by the NO2 donor atoms of the hydrazide Schiff base ligand, the N atom of the pyridine group and an O atom of the symmetry-related unit. The dihedral angles between the pyridine ring and the two phenyl rings of the ligand are 21.4 (3) and 24.0 (2)°. The molecular structure is stabilized by intra-molecular C-H⋯O inter-actions.
引用
收藏
页码:M726 / U176
页数:13
相关论文
共 7 条
[1]   TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].
ALLEN, FH ;
KENNARD, O ;
WATSON, DG ;
BRAMMER, L ;
ORPEN, AG ;
TAYLOR, R .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19
[2]  
[Anonymous], X AREA X RED
[3]   AN EMPIRICAL CORRECTION FOR ABSORPTION ANISOTROPY [J].
BLESSING, RH .
ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 :33-38
[4]  
RAO S, 1990, POLYHEDRON, V16, P1825
[5]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[6]   Structure validation in chemical crystallography [J].
Spek, Anthony L. .
ACTA CRYSTALLOGRAPHICA SECTION D-STRUCTURAL BIOLOGY, 2009, 65 :148-155
[7]   THIOSEMICARBAZONE COMPLEXES OF COPPER(II) - STRUCTURAL AND BIOLOGICAL STUDIES [J].
WEST, DX ;
LIBERTA, AE ;
PADHYE, SB ;
CHIKATE, RC ;
SONAWANE, PB ;
KUMBHAR, AS ;
YERANDE, RG .
COORDINATION CHEMISTRY REVIEWS, 1993, 123 (1-2) :49-71