Metal-organic framework-derived NiSe2-CoSe2@C/Ti3C2Tx composites as electromagnetic wave absorbers

被引:147
作者
Hou, Tianqi [1 ]
Jia, Zirui [1 ,2 ,3 ]
Wang, Bingbing [1 ]
Li, Hanbin [1 ]
Liu, Xuehua [1 ]
Chi, Qingguo [4 ]
Wu, Guanglei [1 ,3 ]
机构
[1] Qingdao Univ, Inst Mat Energy & Environm, Coll Mat Sci & Engn, State Key Lab Biofibers & Ecotext, Qingdao 266071, Peoples R China
[2] Qingdao Univ, Coll Chem & Chem Engn, Qingdao 266071, Shandong, Peoples R China
[3] Qingdao Univ, Weihai Innovat Inst, Qingdao 264200, Shandong, Peoples R China
[4] Harbin Univ Sci & Technol, Key Lab Engn Dielectr & Its Applicat, Minist Educ, Sch Elect & Elect Engn, Harbin 150080, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Ti3C2Tx; Selenization; Multilayer structure; Electromagnetic wave absorption; MICROWAVE-ABSORPTION; CARBON; EFFICIENT; MXENE; PERFORMANCE; NANOSHEETS; HYBRIDS; DESIGN; MOFS;
D O I
10.1016/j.cej.2021.130079
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Two-dimensional metal carbide or nitride materials are considered as a new class of electromagnetic wave absorbing materials due to their unique multilayer structure and metal-like properties. The NiSe2-CoSe2@C/Ti3C2Tx composites were prepared through a facile hydrothermal treatment and selenization reaction. Distinctly, the maximum reflection loss (RL) is -60.46 dB with the mass fraction of NiSe2-CoSe2@C/Ti3C2Tx of 40 wt% at 2.6 mm. The bandwidth of RL < -10 dB reaches up to 5.68 GHz (10.32-16 GHz). The synergistic mechanism of the multiple scattering and multi-interface polarization effects of NiSe2-CoSe2@C compounded with Ti3C2Tx is reviewed to interpret the significant improvement of electromagnetic wave absorption performance. The results indicate that NiSe2-CoSe2@C/Ti3C2Tx composites have potential applications as realistic electromagnetic wave absorbing materials.
引用
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页数:12
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