Synthesis and Crystal Structure of a [70]Fullerene-Pentacene Monoadduct

被引：7
作者：
Shirai, Hitoshi [1 ]
Tajima, Tomoyuki [1 ]
Kubo, Kentaro [1 ]
Nishihama, Takuya [1 ]
Miyake, Hideaki [2 ]
Takaguchi, Yutaka [1 ]
机构：
[1] Okayama Univ, Grad Sch Environm & Life Sci, Kita Ku, 3-1-1 Tsushima Naka, Okayama 7008530, Japan
[2] Yamaguchi Univ, Grad Sch Sci & Engn, 2-16-1 Tokiwadai, Ube, Yamaguchi 7558611, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2016年 / 89卷 / 04期
关键词：
C-60; C-70; FULLERODENDRON; CYCLOADDITION; FABRICATION; FULLERENES; MOLECULES; CHEMISTRY; ADDUCTS;
D O I：
10.1246/bcsj.20150378
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We succeeded in the first isolation of a single pure regioisomer of a C-70-acene monoadduct. 1,9-Diels-Alder monoadducts of C-70 with pentacene derivatives were obtained by not only the Diels-Alder reaction but also a one-pot reaction using stable dihydropentacene derivatives, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), and C-70. The X-ray crystallographic study of a single pure regioisomer 2b confirmed positions of the linkage between C-70 and acenes for the first time, and revealed unique columnar stacks.
引用
收藏
页码：437 / 443
页数：7
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