Crossover SAFT-BACK equation of state for pure CO2 and H2O

被引：25

作者：

Hu, ZQ ^{[1
]}

Yang, JC ^{[1
]}

Li, YG ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem Engn, Beijing 100084, Peoples R China

来源：

FLUID PHASE EQUILIBRIA | 2003年 / 205卷 / 01期

关键词：

crossover theory; equation of state; SAFT-BACK; carbon dioxide; water;

D O I：

10.1016/S0378-3812(02)00307-2

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

In this paper, the crossover statistical associating fluid theory and Boublik-Alder-Chen-Kreglewski (SAFT-BACK) equation of state (EOS) is established. The system-dependent parameters for pure carbon dioxide and water are regressed and their thermodynamic properties are calculated. Then the classical and crossover SAFT-BACK EOSs are compared. For pure carbon dioxide, their calculated deviations are both small. For pure water, the calculated accuracy with the crossover EOS is better than that with the classical EOS. Then some rules about the crossover method are revealed. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：25 / 36

页数：12

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