Single-Wall Carbon Nanotube Latexes

被引:46
作者
Antonietti, Markus [1 ]
Shen, Yanfei [1 ]
Nakanishi, Takashi [1 ,2 ]
Manuelian, Michael [3 ]
Campbell, Robert [3 ]
Gwee, Liang [4 ]
Elabd, Yossef A. [4 ]
Tambe, Nikhil [5 ]
Crombez, Rene [5 ]
Texter, John [1 ,5 ]
机构
[1] Max Planck Inst Colloids & Interfaces, D-14476 Golm, Germany
[2] Natl Inst Mat Sci, Tsukuba, Ibaraki 3050047, Japan
[3] Netzsch Instruments N Amer, Burlington, MA 01803 USA
[4] Drexel Univ, Dept Chem & Biol Engn, Philadelphia, PA 19104 USA
[5] Eastern Michigan Univ, Coatings Res Inst, Sch Engn Technol, Ypsilanti, MI 48197 USA
关键词
carbon nanotubes; charge transport; composites; dielectrics; flexible electronics; latex films; AQUEOUS DISPERSIONS; WATER; FUNCTIONALIZATION; SURFACTANTS; STABILITY; POLYMERIZATION; SOLUBILIZATION; NANOPARTICLES; COMPOSITES; BEHAVIOR;
D O I
10.1021/am900936j
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A nanolatex copolymer (25-30 nm) of an imidalozium bromide acrylate is reported that provides stable waterborne dispersions of single-walled carbon nanotubes (SWCNT) and thermally and electrically conducting coatings that adhere to plastics. This approach to dispersing SWCNT leaps past previous reports by providing stabilization and binder functions simultaneously. Resulting films exhibit 10-fold anisotropy in both thermal and electrical conductivity and appear free of interfacial phonon scattering problems. The electrically conducting networks assembled upon film formation provide a new route to priming plastics for electrodeposition in addition to providing simple antistatic layer formulations. The efficacy of these nanolatexes is assigned to the imidazolium and bromide components shown in other studies to have an affinity for graphene surfaces.
引用
收藏
页码:649 / 653
页数:5
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