On the high efficiency of cis-dichloro [(S)-α-methylbenzylamine](ethylene)platinum(II) as chiral derivatizing agent for the determination of the enantiomeric composition of chiral unsaturated ethers by 195Pt-NMR spectroscopy:: a spectroscopic conformational and configurational characterization in solution of diastereoisomeric complexes cis-dichloro[(S)-α-methylbenzylamine][(S)- and (R)-3-phenyl-3-methoxybut-1-ene]platinum(II)

被引：4

作者：

Uccello-Barretta, G ^{[1
]}

Bernardini, R ^{[1
]}

Balzano, F ^{[1
]}

Lazzaroni, R ^{[1
]}

Salvadori, P ^{[1
]}

机构：

[1] Dipartimento Chim & Chim Ind, CNR, Ctr Studio Macromol Stereordinat & Otticament Att, I-56126 Pisa, Italy

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 605卷 / 01期

关键词：

chiral derivatizing agent; NMR; enantiomeric purity; unsaturated ethers; stereochemistry;

D O I：

10.1016/S0022-328X(00)00255-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The stereochemistry in solution of the diastereoisomeric complexes cis-dichloro[(S)-alpha-methylbenzylamine][(S)- and (R)-3-phenyl-3-methoxybut-1-ene]platinum(II) has been determined by H-1-NMR spectroscopy: in the two species the ethereal ligand is involved by its oxygen atom in the formation of an interligand O ... H-N hydrogen bond with the amine. The remarkable differentiation of the Pt-195 resonances is due to the different positions of amine substituents with respect to the metal. (C) 2000 Published by Elsevier Science S.A. All rights reserved.

引用

页码：68 / 73

页数：6

共 28 条

[1] CHIRAL CYCLOPALLADATED COMPOUNDS FOR ENANTIOMERIC PURITIES OF FUNCTIONALIZED PHOSPHINES BY MEANS OF MULTINUCLEAR NMR [J].