Tetrel Bonding Interactions

被引：204

作者：

Bauza, Antonio ^{[1
]}

Mooibroek, Tiddo J. ^{[2
]}

Frontera, Antonio ^{[1
]}

机构：

[1] Univ Illes Balears, Dept Quim, Crta Valldemossa Km 7-5, Palma De Mallorca 07122, Baleares, Spain

[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

CHEMICAL RECORD | 2016年 / 16卷 / 01期

关键词：

ab initio calculations; carbon bonding; CSD analysis; noncovalent interactions; SIGMA-HOLE BOND; CRYSTAL-STRUCTURE; SOLID-STATE; MOLECULAR-STRUCTURE; PI INTERACTIONS; HYDROGEN-BONDS; S(N)2 REACTION; CARBON-BOND; HALOGEN; COMPLEXES;

D O I：

10.1002/tcr.201500256

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetrel (Tr) bonding is first placed into perspective as a sigma-hole bonding interaction with atoms of the Tr family. An sp(3) R4Tr unit has four sigma-holes with which a Lewis base can form a complex. We then highlight some inspiring crystal structures where Tr bonding is obvious, followed by an account of our own work. We have shown that Tr bonding is ubiquitous in the solid state and we have highlighted that Tr bonding with carbon is possible when C is placed in the appropriate chemical context. We hope that this account serves as an initial guide and source of inspiration for others wishing to exploit this vastly underexplored interaction.

引用

页码：473 / 487

页数：15

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