Fibrous aggregates from dinuclear zinc(II) salphen complexes

被引：38

作者：

Hui, Joseph K. -H. ^{[1
]}

MacLachlan, Mark J. ^{[1
]}

机构：

[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 31期

基金：

加拿大自然科学与工程研究理事会;

关键词：

SCHIFF-BASE MACROCYCLES; BUILDING-BLOCKS; SUPRAMOLECULAR ELECTRONICS; MECHANICAL-PROPERTIES; POLYMER NANOFIBERS; MOLECULAR WIRES; METAL-COMPLEXES; CATALYSIS; SINGLE; POLY(SALPHENYLENEETHYNYLENE)S;

D O I：

10.1039/c0dt00234h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal complexes composed of two zinc(II) salphen units that are bridged by a flexible hydrocarbon chain have been synthesized and characterized. Their self-assembled supramolecular structures were studied with transmission electron microscopy (TEM) and scanning electron microscopy (SEM). It was found that all of the complexes displayed nanofibrillar morphology and that the surface texture and diameter can be altered by the addition of 4,4'-bipyridine and hydrophobic effects, respectively.

引用

页码：7310 / 7319

页数：10

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