Polycyclic phosphiranes:: Synthesis of C-substituted BABAR-Phos compounds

被引：8

作者：

Läng, FB ^{[1
]}

Grützmacher, H ^{[1
]}

机构：

[1] ETH Honggerberg, Dept Chem, Inorgan Chem Lab, CH-8093 Zurich, Switzerland

来源：

CHIMIA | 2003年 / 57卷 / 04期

关键词：

coordination chemistry; phosphanes; phosphiranes; rhodium;

D O I：

10.2533/000942903777679451

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

BABAR-Phos is a very stable polycyclic phosphirane which is easily synthesized in few steps from dibenzosuberenone. BABAR-Phos is remarkably stable and is not oxygenated with O-2 nor does it react with sulfur in boiling toluene. BABAR-Phos can be used as a ligand in homogenous catalysis. Substituents at the carbon of the PC2 heterocycle can be introduced and asymmetric BABAR-Phos were prepared. The coordination chemistry of rhodium complexes containing these as ligands was investigated.

引用

页码：187 / 190

页数：4

共 14 条

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