Reaction of sodium amalgam with carbenium ions species stabilised by two adjacent organometallic moieties

被引：4

作者：

Capon, JF ^{[1
]}

LeBerreCosquer, N ^{[1
]}

Kergoat, R ^{[1
]}

机构：

[1] UNIV BRETAGNE OCCIDENTALE,CNRS,URA 322,EQUIPE CHIM INORGAN MOLEC,F-29285 BREST,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 508卷 / 1-2期

关键词：

carbenium ions; molybdenum clusters; ferrocenyl; ferrocenophane;

D O I：

10.1016/0022-328X(95)05776-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ionic complexes [Cp(2)Mo(2)(CO)(4){mu-eta(2):eta(3)-HC=C-C(H)(Fc)}][BF4] (1) and [{Cp(2)Mo(2)(CO)(4)(mu-eta(2):eta(3)-HC=C-C(H)}(2)Fc][{BF4}(2)] (5) react with Na-Hg in toluene solution. The results are interpreted in terms of a radical mechanism involving intramolecular and intermolecular coupling reactions.

引用

页码：1 / 6

页数：6

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