Conducting Langmuir-Blodgett (LB) films derived from a new tetrathiafulvalene(TTF) derivative with pyridine groups

被引：11

作者：

Jia, CY ^{[1
]}

Zhang, DQ ^{[1
]}

Xu, Y ^{[1
]}

Xu, W ^{[1
]}

Zhu, D ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solids Lab, Beijing 100080, Peoples R China

来源：

SYNTHETIC METALS | 2003年 / 137卷 / 1-3期

关键词：

tetrathiafulvalene; Langmuir-Blodgett films; conductivity;

D O I：

10.1016/S0379-6779(02)00974-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A new tetrathiafulvalene(TTF) derivative - 4,5-bismethylthio-4',5'-bis(3-picolylthio)-tetrathiafulvalene (BMP-TTF) bearing pyridine groups was found to form stable monolayers at the air/water interface with or without the presence of AgNO3. The monolayers can be transferred onto solid substrates with LB technique. Surface pressure-area isotherms, UV-vis spectrum, FT-IR, X-ray photoelectron spectroscopy. and X-ray diffraction were used to characterize the monolayer formation and the transferred LB films. The room temperature conductivities of the LB films are about similar to10(-7)S(.)cm(-1) and after iodine doping, they are increased to similar to10(-3) S(.)cm(-1).

引用

页码：979 / 980

页数：2