Catalytic conversions in water.: Part 9.: High activity of the Pd/dpppr-s Bronsted acid system in the alternating copolymerization of ethene and carbon monoxide {dpppr-s = C3H6-1,3-[P(C6H4-m-SO3Na)2]2}

被引：69

作者：

Verspui, G ^{[1
]}

Papadogianakis, G ^{[1
]}

Sheldon, RA ^{[1
]}

机构：

[1] Delft Univ Technol, Organ Chem & Catalysis Lab, NL-2826 BL Delft, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 03期

关键词：

D O I：

10.1039/a707572c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of alternating copolymers of ethene and carbon monoxide proceeds rapidly in the aqueous phase in the presence of a water-soluble palladium catalyst and a Bronsted acid; activities of >4 kg of polymer per g palladium per hour were observed.

引用

页码：401 / 402

页数：2

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