Design of highly stable and selective core/yolk-shell nanocatalysts-A review

被引：254

作者：

Li, Ziwei ^{[1
,3
]}

Li, Min ^{[2
]}

Bian, Zhoufeng ^{[3
]}

Kathiraser, Yasotha ^{[3
]}

Kawi, Sibudjing ^{[3
]}

机构：

[1] Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Peoples R China

[2] Guizhou Inst Technol, Sch Civil Engn, Guiyang 550003, Peoples R China

[3] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117585, Singapore

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2016年 / 188卷

关键词：

Design; Core/yolk shell; Nanocatalysts; Stability; Selectivity; FISCHER-TROPSCH SYNTHESIS; ONE-POT SYNTHESIS; METAL-ORGANIC FRAMEWORKS; CO OXIDATION; CATALYTIC-ACTIVITY; CARBON NANOTUBES; NICKEL-CATALYSTS; FUEL-CELL; NANOPARTICLE CATALYSTS; TRANSFER HYDROGENATION;

D O I：

10.1016/j.apcatb.2016.01.067

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In recent decades, increasing interests have been put on improving the stability and selectivity of nanocatalysts for clean energy production due to the decrease of fossil fuels. Despite the prominent feature of high catalytic activity, nanocatalysts are prone to sintering. Structural design of nanocatalysts to form core/yolk shell structure has been proven to be the most effective method to enhance their catalytic stability. In this review, design strategies for core/yolk shell nanocatalysts to attain high stability in energy related applications at high temperatures such as hydrocarbon reforming reactions for syngas production and high temperature fuel cells such as SOFC and MCFC are summarized and exemplified with the advancements made in the recent three years. In addition, measures taken to obtain outstanding selectivity for F-T synthesis and C=C bond hydrogenation reactions are also presented. Further, excellent shape and size selectivity design examples are also introduced. Finally, unsolved problems and challenges for core/yolk shell nanocatalysts design are proposed as the final part of this review. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：324 / 341

页数：18

共 143 条

[1] Synthesis and Stability of Pd@CeO2 Core-Shell Catalyst Films in Solid Oxide Fuel Cell Anodes [J].

Adijanto, Lawrence ;

Sampath, Anirudh ;

Yu, Anthony S. ;

Cargnello, Matteo ;

Fornasiero, Paolo ;

Gorte, Raymond J. ;

Vohs, John M. .

ACS CATALYSIS, 2013, 3 (08) :1801-1809

[2] High-temperature-stable catalysts by hollow sphere encapsulation [J].

Arnal, Pablo M. ;

Comotti, Massimiliano ;

Schueth, Ferdi .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (48) :8224-8227

[3] Reaction-Induced Cluster Ripening and Initial Size-Dependent Reaction Rates for CO Oxidation on Ptn/TiO2(110)-(1x1) [J].

Bonanni, Simon ;

Ait-Mansour, Kamel ;

Harbich, Wolfgang ;

Brune, Harald .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (24) :8702-8707

[4] The role of pore size and structure on the thermal stability of gold nanoparticles within mesoporous silica [J].

Bore, MT ;

Pham, HN ;

Switzer, EE ;

Ward, TL ;

Fukuoka, A ;

Datye, AK .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (07) :2873-2880

[5] Study of CO oxidation over TiO2-anatase by simultaneous kinetic and electrical measurements [J].

Bratan, Veronica ;

Munteanu, Cornel ;

Hornoiu, Cristian ;

Papa, Florica ;

Ionescu, Niculae I. .

REACTION KINETICS MECHANISMS AND CATALYSIS, 2014, 112 (01) :51-60

[6] Using MCFC for high efficiency CO2 capture from natural gas combined cycles: Comparison of internal and external reforming [J].

Campanari, Stefano ;

Manzolini, Giampaolo ;

Chiesa, Paolo .

APPLIED ENERGY, 2013, 112 :772-783

[7] Stabilizing metal nanoparticles for heterogeneous catalysis [J].

Cao, Anmin ;

Lu, Rongwen ;

Veser, Goetz .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (41) :13499-13510

[8]

Cargnello M, 2012, SCIENCE, V337, P713, DOI [10.1126/science.1223488, 10.1126/science.1222887]

[9] Multiwalled Carbon Nanotubes Drive the Activity of Metal@oxide Core-Shell Catalysts in Modular Nanocomposites [J].

Cargnello, Matteo ;

Grzelczak, Marek ;

Rodriguez-Gonzalez, Benito ;

Syrgiannis, Zois ;

Bakhmutsky, Kevin ;

La Parola, Valeria ;

Liz-Marzan, Luis M. ;

Gorte, Raymond J. ;

Prato, Maurizio ;

Fornasiero, Paolo .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (28) :11760-11766

[10] Stability of Ni and Rh-Ni catalysts derived from hydrotalcite-like precursors for the partial oxidation of methane [J].

Cesar, Deborah V. ;

Baldanza, Maria A. S. ;

Henriques, Cristiane A. ;

Pompeo, Francisco ;

Santori, Gerardo ;

Munera, John ;

Lombardo, Eduardo ;

Schmal, Martin ;

Cornaglia, Laura ;

Nichio, Nora .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (14) :5616-5626

← 1 2 3 4 5 6 7 8 9 10 →