Experimental confirmation of an iron-gallium multiple bond: Synthesis, structure, and bonding of a ferrogallyne

被引：124
作者：
Su, JR
Li, XW
Crittendon, RC
Campana, CF
Robinson, GH
机构：
[1] UNIV GEORGIA, DEPT CHEM, ATHENS, GA 30602 USA
[2] SIEMENS ENERGY & AUTOMAT INC, ANALYT XRAY DIV, MADISON, WI 53719 USA
来源：
ORGANOMETALLICS | 1997年 / 16卷 / 21期
关键词：
D O I：
10.1021/om970530c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of disodium tetracarbonylferrate, Na-2[Fe(CO)(4)], with [2, 6-bis(2,4, 6-triisopropylphenyl)-phenyl]gallium dichloride, (Mes*2C6H3)GaCl2 (Mes* = 2,4,6-triisopropylphenyl), affords tetracarbonyliron [2,6-bis(2,4,6-triisopropylphenyl)phenyl]gallyne (CO)(4)Fe drop Ga(C(6)H(3)Mes*(2)), as anaerobically stable yellow prism crystals. The title compound offers evidence in support of an iron-gallium triple bond-the first ferrogallyne.
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页码：4511 / 4513
页数：3
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