3D printing of SiC ceramic: Direct ink writing with a solution of preceramic polymers

被引：135

作者：

Chen, Hehao ^{[1
]}

Wang, Xiaofeng ^{[1
,2
]}

Xue, Fengdan ^{[1
]}

Huang, Yujuan ^{[1
]}

Zhou, Kechao ^{[1
]}

Zhang, Dou ^{[1
]}

机构：

[1] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China

[2] Cent S Univ, Sch Mat Sci & Engn, Changsha 410083, Hunan, Peoples R China

来源：

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2018年 / 38卷 / 16期

基金：

中国国家自然科学基金;

关键词：

Direct ink writing; 3D printing; Silicon carbide; Preceramic polymer; Polycarbosilane; SILICON-CARBIDE FIBER; POLYCARBOSILANE FIBER; PYROLYSIS PROCESS; SUSPENSIONS; CONVERSION; SCAFFOLDS; PCS; PRODUCTS; NICALON;

D O I：

10.1016/j.jeurceramsoc.2018.08.009

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

3D structured SiC ceramics with varying feature sizes (100-400 mu m) were achieved by direct ink writing of polycarbosilane (PCS)/n-hexane solution. The rheological properties of the PCS solution and printing parameters were tailored for optimum writing behaviour. The integrity and clear surface of the filaments indicated the printing ability of forming the self-supporting features along with the rapid evaporation of solvent. As-printed 3D structured PCS was processed by oxidative crosslinking and pyrolysis and converted to SiC ceramic. Although strong shrinkage occurred during the pyrolysis, SiC ceramic maintained the original 3D structure. Both proper viscoelasticity of printable solutions and the homogeneous shrinkage in the pyrolysis determine the integrity and feature characteristic of 3D structured SiC using direct ink writing preceramic polymer.

引用

页码：5294 / 5300

页数：7

共 38 条

[11] SYNTHESIS OF CONTINUOUS SILICON-CARBIDE FIBER .2. CONVERSION OF POLYCARBOSILANE FIBER INTO SILICON-CARBIDE FIBERS [J].

HASEGAWA, Y ;

IIMURA, M ;

YAJIMA, S .

JOURNAL OF MATERIALS SCIENCE, 1980, 15 (03) :720-728

[12]

HASEGAWA Y, 1989, J MATER SCI, V24, P1177, DOI 10.1007/BF02397045

[13] SYNTHESIS OF CONTINUOUS SILICON-CARBIDE FIBER .4. THE STRUCTURE OF POLYCARBOSILANE AS THE PRECURSOR [J].

HASEGAWA, Y ;

OKAMURA, K .

JOURNAL OF MATERIALS SCIENCE, 1986, 21 (01) :321-328

[14] EFFECT OF CURING CONDITIONS ON MECHANICAL-PROPERTIES OF SIC FIBER (NICALON) [J].

ICHIKAWA, H ;

TERANISHI, H ;

ISHIKAWA, T .

JOURNAL OF MATERIALS SCIENCE LETTERS, 1987, 6 (04) :420-422

[15] Direct Ink Writing of Silicon Carbide for Microwave Optics [J].

Larson, Chris M. ;

Choi, Justin J. ;

Gallardo, Patricio A. ;

Henderson, Shawn W. ;

Niemack, Michael D. ;

Rajagopalan, Ganesan ;

Shepherd, Robert F. .

ADVANCED ENGINEERING MATERIALS, 2016, 18 (01) :39-45

[16]

Larson R.G., 1999, The Structure and Rheology of Complex Fluids

[17] 3D-Printing of Meso-structurally Ordered Carbon Fiber/Polymer Composites with Unprecedented Orthotropic Physical Properties [J].

Lewicki, James P. ;

Rodriguez, Jennifer N. ;

Zhu, Cheng ;

Worsley, Marcus A. ;

Wu, Amanda S. ;

Kanarska, Yuliya ;

Horn, John D. ;

Duoss, Eric B. ;

Ortega, Jason M. ;

Elmer, William ;

Hensleigh, Ryan ;

Fellini, Ryan A. ;

King, Michael J. .

SCIENTIFIC REPORTS, 2017, 7

[18]

Lewis J. A., 2010, ADV FUNCT MATER, V16, P2193

[19] Colloidal processing of ceramics [J].

Lewis, Jennifer A. .

2000, American Ceramic Soc, Westerville (83)

[20] Direct ink writing of three-dimensional ceramic structures [J].

Lewis, Jennifer A. ;

Smay, James E. ;

Stuecker, John ;

Cesarano, Joseph, III .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2006, 89 (12) :3599-3609

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