A primer for nuclear magnetic relaxation in liquids

被引：14
作者：
Murali, N
Krishnan, V
机构：
[1] Varian NMR Syst, Palo Alto, CA 94304 USA
[2] Univ Calif Lawrence Livermore Natl Lab L 448, Mol Biophys Grp, Biol & Biotechnol Res Program, Livermore, CA 94551 USA
来源：
CONCEPTS IN MAGNETIC RESONANCE PART A | 2003年 / 17A卷 / 01期
关键词：
NMR; spin relaxation; semiclassical theory; equation of motion; motional limits; rate constants; autocorrelation; cross-correlation; EULER-RODRIGUES PARAMETERS; CALRETICULIN P-DOMAIN; CROSS-CORRELATION; SPIN RELAXATION; NMR RELAXATION; TRANSVERSE RELAXATION; RESONANCE RELAXATION; PULSE EXPERIMENTS; GHZ NMR; SYSTEMS;
D O I：
10.1002/cmr.a.10060
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This article is a primer that is intended to serve as a concise source of information for researchers interested in learning relaxation aspects in NMR. Explicit expressions have been derived for the equation of motion of nuclear spins in the solution state. General expressions valid for all motional regimes, including anisotropy of spin interactions and molecular motions, are presented. intricate details that impact the validity of various expressions have been elaborated and efforts have been made to maintain consistent notation. The suitable examples given here should help in the understanding of the concepts developed in the theory. (C) 2003 Wiley Periodicals, Inc.
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收藏
页码：86 / 116
页数：31
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