A primer for nuclear magnetic relaxation in liquids

被引:14
|
作者
Murali, N
Krishnan, V
机构
[1] Varian NMR Syst, Palo Alto, CA 94304 USA
[2] Univ Calif Lawrence Livermore Natl Lab L 448, Mol Biophys Grp, Biol & Biotechnol Res Program, Livermore, CA 94551 USA
来源
CONCEPTS IN MAGNETIC RESONANCE PART A | 2003年 / 17A卷 / 01期
关键词
NMR; spin relaxation; semiclassical theory; equation of motion; motional limits; rate constants; autocorrelation; cross-correlation; EULER-RODRIGUES PARAMETERS; CALRETICULIN P-DOMAIN; CROSS-CORRELATION; SPIN RELAXATION; NMR RELAXATION; TRANSVERSE RELAXATION; RESONANCE RELAXATION; PULSE EXPERIMENTS; GHZ NMR; SYSTEMS;
D O I
10.1002/cmr.a.10060
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This article is a primer that is intended to serve as a concise source of information for researchers interested in learning relaxation aspects in NMR. Explicit expressions have been derived for the equation of motion of nuclear spins in the solution state. General expressions valid for all motional regimes, including anisotropy of spin interactions and molecular motions, are presented. intricate details that impact the validity of various expressions have been elaborated and efforts have been made to maintain consistent notation. The suitable examples given here should help in the understanding of the concepts developed in the theory. (C) 2003 Wiley Periodicals, Inc.
引用
收藏
页码:86 / 116
页数:31
相关论文
共 50 条
  • [21] The effect of spatial variation in surface relaxivity on nuclear magnetic resonance relaxation rates
    Keating, Kristina
    Knight, Rosemary
    GEOPHYSICS, 2012, 77 (05) : E365 - E377
  • [22] The Effect of Diffusion in Internal Gradients on Nuclear Magnetic Resonance Transverse Relaxation Measurements
    Muncaci, S.
    Boboia, S.
    Ardelean, I.
    PROCESSES IN ISOTOPES AND MOLECULES (PIM 2013), 2013, 1565 : 133 - 136
  • [23] Measurement of the true transverse nuclear magnetic resonance relaxation in the presence of field gradients
    Mitchell, J.
    Chandrasekera, T. C.
    Gladden, L. F.
    JOURNAL OF CHEMICAL PHYSICS, 2013, 139 (07)
  • [24] Nuclear magnetic relaxation measurements in Yb-monopnictides
    Oyamada, A
    Hashi, K
    Maegawa, S
    Goto, T
    Li, DX
    Suzuki, T
    Hulliger, F
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1998, 177 : 343 - 344
  • [25] Nuclear magnetic resonance surface relaxation mechanisms of kerogen
    Zhang, Boyang
    Daigle, Hugh
    GEOPHYSICS, 2017, 82 (06) : JM15 - JM22
  • [26] The impact of pore-scale magnetic field inhomogeneity on the shape of the nuclear magnetic resonance relaxation time distribution
    Grombacher, Denys
    Fay, Emily
    Nordin, Matias
    Knight, Rosemary
    GEOPHYSICS, 2016, 81 (05) : EN43 - EN55
  • [27] Dynamics of fluorinated imide-based ionic liquids using nuclear magnetic resonance techniques
    Pranto, Tawhid
    Fraenza, Carla C.
    Philippi, Frederik
    Rauber, Daniel
    Kay, Christopher W. M.
    Welton, Tom
    Greenbaum, Steven G.
    Suarez, Sophia
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2025, 27 (05) : 2462 - 2472
  • [28] Measurements of longitudinal and transverse relaxation times of selected liquids using the EFNMR scanner
    Trybus, Mariusz
    PRZEGLAD ELEKTROTECHNICZNY, 2020, 96 (10): : 115 - 118
  • [29] Nuclear magnetic resonance diffusion with surface relaxation in porous media
    Valfouskaya, A
    Adler, PM
    Thovert, JF
    Fleury, M
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 295 (01) : 188 - 201
  • [30] Nuclear magnetic relaxation rate in iron-pnictide superconductors
    Kariyado, T.
    Ogata, M.
    PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS, 2010, 470 : S334 - S335