Syntheses and characterization of copper complexes of the ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (uns-penp) and derivatives

被引：46
|
作者：
Schatz, M
Leibold, M
Foxon, SP
Weitzer, M
Heinemann, FW
Hampel, F
Walter, O
Schindler, S
机构：
[1] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany
[2] Forschungszentrum Karlsruhe, ITC CPV, D-76021 Karlsruhe, Germany
[3] Univ Erlangen Nurnberg, Inst Inorgan Chem, D-91058 Erlangen, Germany
来源：
DALTON TRANSACTIONS | 2003年 / 08期
关键词：
D O I：
10.1039/b208740e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Synthesis and structural characterization of the copper(I) and copper(II) complexes of the tripodal tetradentate ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (uns-penp) are reported as well as the reactivity of the copper(I) uns-penp complex towards dioxygen. Uns-penp can be easily modified and two copper(II) complexes of these derivatives have been structurally characterized. In the copper(II) complex of an amide derivative of uns-penp, [Cu(acetyl-uns-penp)Cl]ClO4, it is evident that the amide nitrogen is no longer truly sp(2) hybridised, a consequence of a weak interaction with the copper(II) ion.
引用
收藏
页码：1480 / 1487
页数：8
相关论文
共 50 条
  • [1] Iron and cobalt complexes with the ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (uns-penp) and derivatives
    Nebe, Thomas
    Xu, Jing-Yuan
    Beitat, Alexander
    Wuertele, Christian
    Walter, Olaf
    Serafin, Michael
    Schindler, Siegfried
    INORGANICA CHIMICA ACTA, 2010, 363 (12) : 2965 - 2970
  • [2] Characterization of copper complexes with derivatives of the ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (uns-penp) and their reactivity towards oxygen
    Brueckmann, Tim
    Becker, Jonathan
    Wuertele, Christian
    Seuffert, Marcel Thomas
    Heuler, Dominik
    Mueller-Buschbaum, Klaus
    Weiss, Morten
    Schindler, Siegfried
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2021, 223
  • [3] Immobilization of a copper complex based on the tripodal ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (uns-penp)
    Brueckmann, Tim
    Becker, Jonathan
    Turke, Kevin
    Smarsly, Bernd
    Weiss, Morten
    Marschall, Roland
    Schindler, Siegfried
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2021, 647 (05): : 560 - 571
  • [4] Syntheses and characterization of copper complexes with the ligand 2-aminoethyl(2-pyridylmethyl)-1,2-ethanediamine (apme)
    Utz, Diana
    Kisslinger, Sandra
    Hampel, Frank
    Schindler, Siegfried
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2008, 102 (5-6) : 1236 - 1245
  • [5] Synthesis and characterization of ruthenium(II) complexes bearing the bis(2-pyridylmethyl)amine ligand
    Gibson, DH
    Wu, JG
    Mashuta, MS
    INORGANICA CHIMICA ACTA, 2006, 359 (01) : 309 - 319
  • [6] [(6-Methyl-2-pyridylmethyl)(2-pyridylmethyl)amine][(2-pyridylmethyl)amine]copper(II) bis(perchlorate)
    Butcher, Ray J.
    Tesema, Yohannes T.
    Yisgedu, Teshome B.
    Gultneh, Yilma
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M74 - U732
  • [7] Synthesis and characterization of copper(I) complexes containing tri(2-pyridylmethyl)amine ligand
    Sodio C. N. Hsu
    Sam S. C. Chien
    Howard H. Z. Chen
    Michael Y. Chiang
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2007, 54 (03) : 685 - 692
  • [8] Syntheses, structures, and O2-reactivities of copper(I) complexes with bis(2-pyridylmethyl)amine and bis(2-quinolylmethyl)amine tridentate ligands
    Kunishita, Atsushi
    Osako, Takao
    Tachi, Yoshimitsu
    Teraoka, Junji
    Itoh, Shinobu
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2006, 79 (11) : 1729 - 1741
  • [9] Syntheses, structures, and O2-reactivities of copper(I) complexes with bis(2-pyridylmethyl)amine and bis(2-quinolylmethyl)amine tridentate ligands
    Kunishita, Atsushi
    Osako, Takao
    Tachi, Yoshimitsu
    Teraoka, Junji
    Itoh, Shinobu
    Bulletin of the Chemical Society of Japan, 2006, 79 (11): : 1729 - 1741
  • [10] (Acetonitrile)[bis(2-pyridylmethyl)-amine]bis(perchlorato)copper(II)
    Butcher, Ray J.
    Tesema, Yohannes T.
    Yisgedu, Teshome B.
    Gultneh, Yilma
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M233 - U2221
12345