Self-assembly of hydrogen-bonded supramolecular structures based on the neutral pseudo-macrocyclic complex bis(dimethylglyoximato) copper (II)

被引：19

作者：

Bishop, MM

Lee, AHW

Lindoy, LF ^{[1
]}

Turner, P

Skelton, BW

White, AH

机构：

[1] Univ Sydney, Sch Chem, Ctr Heavy Met Res, Sydney, NSW 2006, Australia

[2] Sydney Grammar Sch, Darlinghurst, NSW 2010, Australia

[3] Univ Western Australia, Crawley, WA 6009, Australia

来源：

SUPRAMOLECULAR CHEMISTRY | 2005年 / 17卷 / 1-2期

关键词：

engineering; self-assembly; supramolecular; copper(II);

D O I：

10.1080/10610270412331328844

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three new complexes based on the neutral pseudo-macrocyclic complex bis(dimethylglyoximato)copper(II) and the substituted pyridines, 4-phenylpyridine, 3-pyridin-4-ylpropan-1-ol and isonicotinamide, which occupy a fifth coordination site on the copper, are described. The usefulness of such complexes in building supra-molecular arrays is examined. The complex containing 3-pyridin-4-ylpropan-1-ol forms hydrogen-bonded chains that, lying across one another, form layers within the crystal. The isonicotinamide-containing complex yields a host-guest assembly that incorporates channels containing guest molecules. The prospect of 'tuning' the size of the channel is discussed.

引用

页码：37 / 45

页数：9

共 28 条

[1] Two-fold interpenetration of 3-D nets assembled via three-co-ordinate silver(I) ions and amide-amide hydrogen bonds [J].