The kinetics of the reaction between cyclopentene and aqueous hydrogen peroxide under phase-transfer catalysis

被引：5

作者：

Meshechkina, A. E. ^{[1
]}

Mel'nik, L. V. ^{[1
]}

Rybina, G. V. ^{[1
]}

Srednev, S. S. ^{[1
]}

Moskvichev, Yu. A. ^{[1
]}

Shevchuk, A. S. ^{[1
]}

机构：

[1] Yaroslavl State Tech Univ, Yaroslavl, Russia

来源：

PETROLEUM CHEMISTRY | 2015年 / 55卷 / 01期

关键词：

cyclopentene; hydrogen peroxide; 1,2-epoxycyclopentane; 1,2-cyclopentanediol; phase-transfer catalysis; kinetics; reaction rate; mathematical model; EPOXIDATION;

D O I：

10.1134/S0965544114030086

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The kinetics of the reaction between cyclopentene and an aqueous solution of hydrogen peroxide under phase-transfer catalysis conditions has been studied. The activation energies of the successive stages of cyclopentene epoxidation to 1,2-epoxycyclopentane and the hydration of the resulting epoxide to 1,2-cyclopentanediol have been found, and the orders of the reactions with respect to the reactants have been determined. A mathematical model of the process that adequately describes the available experimental data in the entire range of reactant concentrations has been proposed.

引用

页码：51 / 56

页数：6

共 10 条

[1]

Dovganyuk T. V., 1990, NEFTEKHIMIYA, V30, P602

[2]

Kasyan L. I., 2003, ALICYCLIC EPOXY COMP

[3] Synthesis of 1,2-epoxycyclopentane and/or 1,2-cyclopentanediol by oxidation of cyclopentene with aqueous solution of hydrogen peroxide [J].