Iridium-catalysed amine alkylation with alcohols in water

被引:207
作者
Saidi, Ourida [1 ]
Blacker, A. John [2 ,3 ]
Farah, Mohamed M. [2 ,3 ]
Marsden, Stephen P. [2 ,3 ]
Williams, Jonathan M. J. [1 ]
机构
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England
[3] Univ Bath, Inst Proc Res & Dev, Bath BA2 7AY, Avon, England
基金
英国工程与自然科学研究理事会;
关键词
BORROWING HYDROGEN METHODOLOGY; ASTERISK-IR COMPLEX; DYNAMIC KINETIC RESOLUTION; N-ALKYLATION; EFFICIENT CATALYSTS; SECONDARY ALCOHOLS; AROMATIC-AMINES; HETEROCYCLIZATION; MONOALKYLATION; AMINATION;
D O I
10.1039/b923083a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Amines have been directly alkylated with alcohols using 1 mol% [Cp*IrI2](2) catalyst in water in the absence of base or additives.
引用
收藏
页码:1541 / 1543
页数:3
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