Iridium-catalysed amine alkylation with alcohols in water

被引：208

作者：

Saidi, Ourida ^{[1
]}

Blacker, A. John ^{[2
,3
]}

Farah, Mohamed M. ^{[2
,3
]}

Marsden, Stephen P. ^{[2
,3
]}

Williams, Jonathan M. J. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

[3] Univ Bath, Inst Proc Res & Dev, Bath BA2 7AY, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 09期

基金：

英国工程与自然科学研究理事会;

关键词：

BORROWING HYDROGEN METHODOLOGY; ASTERISK-IR COMPLEX; DYNAMIC KINETIC RESOLUTION; N-ALKYLATION; EFFICIENT CATALYSTS; SECONDARY ALCOHOLS; AROMATIC-AMINES; HETEROCYCLIZATION; MONOALKYLATION; AMINATION;

D O I：

10.1039/b923083a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Amines have been directly alkylated with alcohols using 1 mol% [Cp*IrI2](2) catalyst in water in the absence of base or additives.

引用

页码：1541 / 1543

页数：3

共 35 条

[21] Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology [J].

Hamid, M. Haniti S. A. ;

Allen, C. Liana ;

Lamb, Gareth W. ;

Maxwell, Aoife C. ;

Maytum, Hannah C. ;

Watson, Andrew J. A. ;

Williams, Jonathan M. J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) :1766-1774

[22] Borrowing hydrogen in the activation of alcohols [J].

Hamid, Malai Haniti S. A. ;

Slatford, Paul A. ;

Williams, Jonathan M. J. .

ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (10) :1555-1575

[23] Ruthenium catalysed N-alkylation of amines with alcohols [J].

Hamid, Malai Haniti S. A. ;

Williams, Jonathan M. J. .

CHEMICAL COMMUNICATIONS, 2007, (07) :725-727

[24] Ruthenium-catalysed synthesis of tertiary amines from alcohols [J].

Haniti, M. ;

Hamid, S. A. ;

Williams, Jonathan M. J. .

TETRAHEDRON LETTERS, 2007, 48 (47) :8263-8265

[25] A general ruthenium-catalyzed synthesis of aromatic Amines [J].

Hollmann, Dirk ;

Baehn, Sebastian ;

Tillack, Annegret ;

Beller, Matthias .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (43) :8291-8294

[26] An improved ruthenium catalyst for the environmentally benign amination of primary and secondary alcohols [J].

Hollmann, Dirk ;

Tillack, Annegret ;

Michalik, Dirk ;

Jackstell, Ralf ;

Beller, Matthias .

CHEMISTRY-AN ASIAN JOURNAL, 2007, 2 (03) :403-410

[27] Genotoxic Impurities [J].

Laird, Trevor .

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2009, 13 (03) :363-363

[28] Selective N-monoalkylation of anilines catalyzed by a cationic ruthenium(II) compound [J].

Naskar, Sipra ;

Bhattacharjee, Manish .

TETRAHEDRON LETTERS, 2007, 48 (19) :3367-3370

[29] Transition metal catalysed reactions of alcohols using borrowing hydrogen methodology [J].

Nixon, Tracy D. ;

Whittlesey, Michael K. ;

Williams, Jonathan M. J. .

DALTON TRANSACTIONS, 2009, (05) :753-762

[30] Iridium catalysed synthesis of piperazines from diols [J].

Nordstrom, Lars Ulrik ;

Madsen, Robert .

CHEMICAL COMMUNICATIONS, 2007, (47) :5034-5036

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