Characterization of a natural substituted pyromorphite

被引:34
作者
Botto, IL [1 ]
Barone, VL [1 ]
Castiglioni, JL [1 ]
Schalamuk, IB [1 ]
机构
[1] NATL UNIV LA PLATA, FAC CIENCIAS NAT & MUSEO, INREMI, RA-1900 LA PLATA, ARGENTINA
关键词
D O I
10.1023/A:1018667428762
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Pyromorphite (Pb-5(PO4)(3)Cl) which occurs in the oxidation zone of a polymetallic Pb-Zn-Ag-Au vein in Paramillos de Uspallata, Mendoza, Argentina, was studied by scanning electron microscopy (including energy dispersive analysis of X-rays (EDAX) electron microprobe), i.r. and Raman spectroscopies and X-ray powder diffraction analysis. The substitution of Pb by Ca and Ba and Cl by OH, respectively, have been detected. In addition, i.r. absorption bands for the CO32- nu(3)-mode have been clearly identified. They are attributed to the CO32- for PO4-3 substitution in the structure. The composition is regarded as an indication of the paragenesis of the host rocks and the mineralogy of the deposit.
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收藏
页码:6549 / 6553
页数:5
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