SPEEK Membrane of Ultrahigh Stability Enhanced by Functionalized Carbon Nanotubes for Vanadium Redox Flow Battery

被引：61
作者：
Ding, Mei [1 ]
Ling, Xiao [2 ]
Yuan, Du [3 ]
Cheng, Yuanhang [2 ]
Wu, Chun [1 ]
Chao, Zi-Sheng [1 ]
Sun, Lidong [4 ,5 ]
Yang, Chuanwei [2 ]
Jia, Chuankun [1 ,2 ,5 ]
机构：
[1] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha, Hunan, Peoples R China
[2] Chinese Acad Sci, Inst Met Res, Shenyang, Liaoning, Peoples R China
[3] Natl Univ Singapore, Dept Mat Sci & Engn, Fac Engn, Singapore, Singapore
[4] Chongqing Univ, Sch Mat Sci & Engn, State Key Lab Mech Transmiss, Chongqing, Peoples R China
[5] Nankai Univ, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin, Peoples R China
来源：
FRONTIERS IN CHEMISTRY | 2018年 / 6卷
基金：
中国国家自然科学基金;
关键词：
redox flow battery; vanadium redox flow battery; ion exchange membrane; sulfonated poly(ether ether ketone); carbon nanotube; POLY(ETHER ETHER KETONE); PROTON-EXCHANGE MEMBRANES; RESEARCH-AND-DEVELOPMENT; HYBRID MEMBRANE; NAFION MEMBRANE; COMPOSITE MEMBRANE; PERFORMANCE; PROGRESS;
D O I：
10.3389/fchem.2018.00286
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Proton exchange membrane is the key factor of vanadium redox flow battery (VRB) as their stability largely determine the lifetime of the VRB. In this study, a SPEEK/MWCNTs-OH composite membrane with ultrahigh stability is constructed by blending sulfonated poly(ether ether ketone) (SPEEK) with multi-walled carbon nanotubes toward VRB application. The carbon nanotubes disperse homogeneously in the SPEEK matrix with the assistance of hydroxyl group. The blended membrane exhibits 94.2 and 73.0% capacity retention after 100 and 500 cycles, respectively in a VRB single cell with coulombic efficiency of over 99.4% at 60 mA cm(-2) indicating outstanding capability of reducing the permeability of vanadium ions and enhancing the transport of protons. The ultrahigh stability and low cost of the composite membrane make it a competent candidate for the next generation larger-scale vanadium redox flow battery.
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页数：9
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共 35 条
  • [1] Surface observation of solvent-impregnated Nafion membrane with atomic force microscopy
    Affoune, AM
    Yamada, A
    Umeda, M
    [J]. LANGMUIR, 2004, 20 (17) : 6965 - 6968
  • [2] SPEEK/Graphene oxide nanocomposite membranes with superior cyclability for highly efficient vanadium redox flow battery
    Dai, Wenjing
    Shen, Yi
    Li, Zhaohua
    Yu, Lihong
    Xi, Jingyu
    Qiu, Xinping
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (31) : 12423 - 12432
  • [3] Sulfonated Poly(Ether Ether Ketone)/Graphene composite membrane for vanadium redox flow battery
    Dai, Wenjing
    Yu, Lihong
    Li, Zhaohua
    Yan, Jia
    Liu, Le
    Xi, Jingyu
    Qiu, Xinping
    [J]. ELECTROCHIMICA ACTA, 2014, 132 : 200 - 207
  • [4] Tunable Nanochannels along Graphene Oxide/Polymer Core-Shell Nanosheets to Enhance Proton Conductivity
    He, Guangwei
    Chang, Chaoyi
    Xu, Mingzhao
    Hu, Shen
    Li, Lingqiao
    Zhao, Jing
    Li, Zhen
    Li, Zongyu
    Yin, Yongheng
    Gang, Mingyue
    Wu, Hong
    Yang, Xinlin
    Guiver, Michael D.
    Jiang, Zhongyi
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (48) : 7502 - 7511
  • [5] The effect of equivalent weight, temperature, cationic forms, sorbates, and nanoinorganic additives on the sorption behavior of Nafion®
    Jalani, NH
    Datta, R
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2005, 264 (1-2) : 167 - 175
  • [6] Hydration of Nafion® studied by AFM and X-ray scattering
    James, PJ
    Elliott, JA
    McMaster, TJ
    Newton, JM
    Elliott, AMS
    Hanna, S
    Miles, MJ
    [J]. JOURNAL OF MATERIALS SCIENCE, 2000, 35 (20) : 5111 - 5119
  • [7] High-energy density nonaqueous all redox flow lithium battery enabled with a polymeric membrane
    Jia, Chuankun
    Pan, Feng
    Zhu, Yun Guang
    Huang, Qizhao
    Lu, Li
    Wang, Qing
    [J]. SCIENCE ADVANCES, 2015, 1 (10):
  • [8] Sulfonated Poly(Ether Ether Ketone)/Functionalized Carbon Nanotube Composite Membrane for Vanadium Redox Flow Battery Applications
    Jia, Chuankun
    Cheng, Yuanhang
    Ling, Xiao
    Wei, Guanjie
    Liu, Jianguo
    Yan, Chuanwei
    [J]. ELECTROCHIMICA ACTA, 2015, 153 : 44 - 48
  • [9] In Situ X-ray Near-Edge Absorption Spectroscopy Investigation of the State of Charge of All-Vanadium Redox Flow Batteries
    Jia, Chuankun
    Liu, Qi
    Sun, Cheng-Jun
    Yang, Fan
    Ren, Yang
    Heald, Steve M.
    Liu, Yadong
    Li, Zhe-Fei
    Lu, Wenquan
    Xie, Jian
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (20) : 17920 - 17925
  • [10] A multilayered membrane for vanadium redox flow battery
    Jia, Chuankun
    Liu, Jianguo
    Yan, Chuanwei
    [J]. JOURNAL OF POWER SOURCES, 2012, 203 : 190 - 194
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