Theoretical study of Diels-Alder reactions of azaphospha (ARSA) benzenes

被引：0

作者：

Pacureanu, L ^{[1
]}

Mracec, M ^{[1
]}

机构：

[1] Romanian Acad, Inst Chem, Timisoara 300223, Romania

来源：

REVISTA DE CHIMIE | 2003年 / 54卷 / 05期

关键词：

1,3-lambda(3)-azaarsabenzene 1,3 lambda(3)-azaphosphabenzene; Diels-Alder reactions;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A theoretical study of geometry and reactivity of 2,4,6-triphenyl-1,3-lambda(3)-azaarsabenzene and 2,4,6-triphenyl-1,3-lambda(3)-azaphosphabenzene-in Diels-Alder reactions with less reactive alkynes were performed. The computed values for molecular geometries were close to the experimental ones and the thermodynamic stability showed a higher reactivity of 1,3-lambda(3)-azaarsabenzene and 1,3-lambda(3)-azaphosphabenzene.

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收藏

页码：399 / 401

页数：3

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