Chemical composition of precipitation at Mt. Vesuvius and Vulcano Island, Italy: volcanological and environmental implications

被引:16
作者
Madonia, Paolo [1 ]
Liotta, Marcello [1 ]
机构
[1] Ist Nazl Geofis & Vulcanol, Sez Palermo, I-90146 Palermo, Italy
关键词
Chemistry; Fumarole; Precipitation; Vesuvius; Vulcano Island; ETNA; DEPOSITION; VOLCANOS; FLUORINE; PLUME;
D O I
10.1007/s12665-009-0333-9
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Natural precipitation and water samples from passive devices were collected at Mt. Vesuvius and Vulcano Island, Italy, during the period 2004-2006, in order to investigate its possible interactions with fumarolic gases. Evidence of chemical reactions between fumarolic fluids and rain samples before and after its deposition into the sampling devices was found at Vulcano Island. Very low pH values ( down to 2.5) and significant amounts of chlorine and sulfate ( up to 22 mEq/l) were measured at sampling points located close to the fumarolic field. In contrast, anthropogenic contributions and/or dissolution of aerosols ( both maritime and continental) influence the chemistry of rainwaters at Mt. Vesuvius, which show inter-annual variations that are highly consistent with those recorded at the coastal site at Vulcano Island. Chemistry of waters directly exposed to fumarolic fluids may then give useful information about its temporal evolution, holding the signal of the "maximum'' chemical event occurred in the meanwhile. In addition, the observation of the health status of vegetation colonizing the immediate surroundings of the fumarolic fields, due to its strong dependence on the interactions with these fluids, may work as a possible biomarker of volcanic activity.
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页码:159 / 171
页数:13
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