Theoretical investigation of zero field splitting parameter of Cr3+ doped diammonium hexaaqua magnesium sulfate

被引：0

作者：

Kripal, Ram ^{[1
]}

Yadav, Awadhesh Kumar ^{[1
]}

机构：

[1] Univ Allahabad, Dept Phys, EPR Lab, Allahabad 211002, Uttar Pradesh, India

来源：

PHYSICA B-CONDENSED MATTER | 2015年 / 456卷

关键词：

Inorganic compounds; Crystal fields; Electron paramagnetic resonance; Optical properties; SPIN-HAMILTONIAN PARAMETERS; SUPERPOSITION MODEL ANALYSIS; LOCAL DISTORTION; ENERGY-LEVELS; 3D(N) IONS; EPR; SITE;

D O I：

10.1016/j.physb.2014.08.046

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The zero field splitting parameter D of Cr3+ doped diammonium hexaaqua magnesium sulfate (DHMS) are calculated with perturbation formula using crystal field (CF) parameters from superposition model. The theoretically calculated ZFS parameters for Cr3+ in DHMS single crystal are compared with the experimental value obtained by electron paramagnetic resonance (EPR). The theoretical ZFS parameter D is similar to that from experiment. The energy band positions of optical absorption spectra of Cr3+ doped DHMS single crystal are calculated with CFA package, which are in good match with experimental values. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：159 / 162

页数：4

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