Fabrication and release behavior of nitrapyrin Microcapsules: Using modified melamine-formaldehyde resin as shell material

被引:29
作者
Zhang Zhong-qing [1 ]
Gao Qiang [1 ]
Yang Jing-min [1 ]
Wang Yan [1 ]
Yang Jing-yi [2 ]
Zhang Xue [1 ]
Feng Guo-zhong [1 ]
Cheng Zhi-Qiang [1 ]
Wang Shao-jie [1 ]
Su Hong-ge [1 ]
机构
[1] Jilin Agr Univ, Coll Resources & Environm Sci, Key Lab Soil Resource Sustainable Utilizat Jilin, Changchun 130118, Jilin, Peoples R China
[2] Agr & Agri Food Canada, Greenhouse & Proc Crops Res Ctr, Harrow, ON N0R 1G0, Canada
关键词
Nitrification inhibitor; Nitrapyrin; Microcapsule; Release behavior; NITRIFICATION INHIBITORS; MECHANICAL-PROPERTIES; ORGANIC-MATTER; ENCAPSULATION; SOLVENT; MICROENCAPSULATION; CHLORPYRIFOS; POLYELECTROLYTE; POLYMERIZATION; MICROSPHERES;
D O I
10.1016/j.scitotenv.2019.135394
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
As a commonly used nitrification inhibitor, nitrapyrin can significantly improve the utilization of nitrogen in soils. However, the effectiveness of the traditional dosage form of nitrapyrin is reduced by soil adsorption. In this study, nitrapyrin was encapsulated into a melamine-formaldehyde resin microcapsule with good dispersion and release behavior using an in situ polymerization method. The nitrapyrin microcapsules were characterized using Fourier transform infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy, transmission electron microscopy, and particle-size analysis. The results indicated that the microcapsules had a spherical-shell structure, a uniform morphology with nanoscale micropores on the surface, and a decent nitrapyrin loading content (67.19%). Tests revealed that the release behavior of the nitrapyrin microcapsules was outstanding and conformed to the double-release kinetic model. These results of this study indicate that the nitrapyrin microcapsules can be applied as nitrification inhibitors with beneficial environmental effects and high efficacy. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页数:9
相关论文
共 59 条
[1]   Optimization of emulsification procedure for mutual maximizing the encapsulation and exergy efficiencies of fish oil microencapsulation [J].
Aghbashlo, Mortaza ;
Mobil, Hossien ;
Rafiee, Shahin ;
Madadlou, Ashkan .
POWDER TECHNOLOGY, 2012, 225 :107-117
[2]  
Ali R, 2008, PAK J BOT, V40, P1053
[3]   Effect of the shell-forming polymer ratio on the encapsulation of tea tree oil by complex coacervation as a natural biocide [J].
Angeles Perez-Liminana, Maria ;
Paya-Nohales, Federico J. ;
Aran-Ais, Francisca ;
Orgiles-Barcelo, Cesar .
JOURNAL OF MICROENCAPSULATION, 2014, 31 (02) :176-183
[4]   Modification of Urea-Formaldehyde Microcapsules With Lignosulfonate-Ca as Co-Polymer for Encapsulation of Acetochlor [J].
Bai, Wenying ;
Wang, Yan ;
Song, Xiaoli ;
Jin, Xiaoyang ;
Guo, Xiaohong .
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2014, 51 (09) :737-742
[5]  
Baurk D. R., 1980, J POLYM SCI POLYM PH, V1997-2014
[6]   Ultrasound assisted in situ emulsion polymerization for polymer nanocomposite: A review [J].
Bhanvase, B. A. ;
Sonawane, S. H. .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2014, 85 :86-107
[7]   Influence of nitrification inhibitors on nitrification and nitrous oxide (N2O) emission from a clay loam soil fertilized with urea [J].
Chen, Deli ;
Suter, Helen C. ;
Islam, Arshad ;
Edis, Robert .
SOIL BIOLOGY & BIOCHEMISTRY, 2010, 42 (04) :660-664
[8]   Fabrication of hollow melamine-formaldehyde microcapsules from microbubble templates [J].
Daiguji, Hirofumi ;
Makuta, Toshinori ;
Kinoshita, Hiroki ;
Oyabu, Takayuki ;
Takemura, Fumio .
JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (30) :8879-8884
[9]  
Degenhardt R.F., 2016, Crop Forage Turfgrass Manage, V2, P1
[10]   The Microencapsulation of Terbinafine via In Situ Polymerization of Melamine-Formaldehyde and Their Application to Cotton Fabric [J].
Erkan, Gokhan ;
Sariisik, Merih ;
Pazarlioglu, Nurdan Kasikara .
JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 118 (06) :3707-3714