A Liquid-Crystalline Single-Molecule Magnet with Variable Magnetic Properties

被引：128
作者：
Gonidec, Mathieu [1 ]
Luis, Fernando [2 ,3 ]
Vilchez, Alex [4 ]
Esquena, Jordi [4 ]
Amabilino, David B. [1 ]
Veciana, Jaume [1 ]
机构：
[1] Inst Ciencia Mat Barcelona, Networking Res Ctr Bioengn Biomat & Nanomed CIBER, Dept Nanociencia Mol & Mat Organ, CSIC, Bellaterra 08193, Spain
[2] Univ Zaragoza, Inst Ciencia Mat Aragon, CSIC, E-50009 Zaragoza, Spain
[3] Univ Zaragoza, Dept Fis Mat Condensada, E-50009 Zaragoza, Spain
[4] CSIC, Inst Quim Avancada Catalunya, Barcelona, Spain
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 09期
关键词：
lanthanides; liquid crystals; magnetic properties; metallomesogens; single-molecule studies; CHARGE-TRANSPORT PROPERTIES; COMPLEXES; BIS(PHTHALOCYANINATO)TERBIUM;
D O I：
10.1002/anie.200905007
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A terbium double-decker phthalocyanine complex has been prepared and characterized. The mesomorphism of the liquidcrystalline complex is used as a tool to reversibly adjust its magnetic properties, thus allowing the coexistence of two different relaxation processes, which can be reversibly modified by simple thermal treatments, to be observed. © 2010 Wlley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：1623 / 1626
页数：4
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