Yellow MgV2O6•2H2O nanophosphor synthesized by a water-assisted solid-state reaction (WASSR) method at low temperature below 80 °C

被引:5
作者
Kim, Sun Woog [1 ,2 ]
Abe, Yusuke [1 ]
Watanabe, Mizuki [1 ]
Hasegawa, Takuya [1 ,3 ]
Muto, Masaru [1 ]
Toda, Ayano [1 ]
Ishigaki, Tadashi [1 ]
Uematsu, Kazuyoshi [1 ]
Toda, Kenji [1 ]
Sato, Mineo [4 ]
Kawakami, Emiko
Koide, Junko [5 ]
Toda, Masako [5 ]
Kudo, Yoshiaki [5 ]
Masui, Toshiyuki [6 ]
Masaki, Takaki [7 ]
Yoon, Dae Ho [7 ]
机构
[1] Niigata Univ, Grad Sch Sci & Technol, 8050 Ikarashi 2 Nocho, Niigata 9502181, Japan
[2] Sejong Univ, Dept Nanotechnol & Adv Mat Engn, 209 Neungdong Ro, Seoul 05006, South Korea
[3] Kochi Univ, Fac Agr & Marine Sci, Dept Marine Resource Sci, 200 Otsu, Nankoku, Koch 7838502, Japan
[4] Niigata Univ, Dept Chem & Chem Engn, 8050 Ikarashi 2 Nocho, Niigata 9502181, Japan
[5] N Luminescence Corp, 8867-3 Ikarashi 2 Nocho, Niigata 9502101, Japan
[6] Tottori Univ, Fac Engn, 4-101 Koyama Cho Minami, Tottori 6808550, Japan
[7] Sungkyunkwan Univ, Sch Adv Mat Sci & Engn, Kyunggi Do 400746, South Korea
关键词
Nanophosphors; Water-assisted solid-state reaction method; Low-temperature synthesis; MgV2O6 center dot 2H(2)O; Crystal structure; BATIO3; NANOPARTICLES; PHOSPHORS;
D O I
10.1016/j.dyepig.2017.06.024
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Magnesium metavanadate dihydrate (MgV2O6.2H(2)O) was synthesized as a nanophosphor by a water assisted solid-state reaction (WASSR) method, and its crystal structure and luminescence properties were investigated in detail. MgV2O6.2H(2)O has an orthorhombic structure with space group Pnma. In the crystal structure, the MgO6 octahedra and VO4 tetrahedra formed a layered structure in the direction of the b axis, and the VO4 tetrahedra formed a chain structure along the a axis. The nanophosphor showed broad and strong optical absorption in the near-ultraviolet region and exhibited a broad yellow emission peak at 563 nm. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:339 / 344
页数:6
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