High yield hollow carbon cubes with excellent microwave absorption property at a low loading ratio

被引:19
作者
Yuan, Chao [1 ]
Wu, Wen-Wen [1 ]
Liu, Yuan [2 ]
Wang, Zhuo [3 ]
Wang, Yang
Han, Lu-Lu
Zhou, Quan [1 ]
Liu, Jin-Qiu [1 ]
Liu, Peng [1 ]
机构
[1] Shaanxi Normal Univ, Sch Phys & Informat Technol, Xian 710062, Peoples R China
[2] Fenghua Adv Technol Holding Co LTD, Zhaoqing 526040, Peoples R China
[3] Changan Univ, Sch Mat Sci & Engn, Xian 710064, Peoples R China
基金
中国国家自然科学基金;
关键词
Hollow carbon cubes; High yield; Low loading ratio; EMW dissipation Mechanism; EMW Absorption performance; ELECTROMAGNETIC-WAVE ABSORPTION; HIGH-PERFORMANCE; BROAD-BAND; OXYGEN REDUCTION; CORE-SHELL; LIGHTWEIGHT; COMPOSITES; MICROSPHERES; NANOCOMPOSITES; NANOPARTICLES;
D O I
10.1016/j.carbon.2022.04.007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High yielding synthesis of hollow carbon cubes (HCCs) was realized by using easily available NaCl cubes as templates in a simple way. The cubic carbon shells featuring an average side length of 3.5 mm, a thickness of 22.9 nm and the presence of macro and mesopores in the material, endow the HCCs/paraffin composites with an appropriate balance between good impedance matching and strong loss capacity. Superior electromagnetic wave (EMW) absorption performance was obtained at a very low loading ratio of 1.5 wt% of the HCCs. The composite having 4.5 mm thickness gave the maximum reflection loss of -46.0 dB at 7.8 GHz. At a thickness of 2.6 mm, a maximum effective absorption bandwidth of 6.6 GHz was achieved. Further investigation on the EMW dissipation mechanism of HCCs surrounding polarization relaxation and conductive loss was conducted. The integrity of the hollow structure plays a dominant role during EMW dissipation. The present study provides easy processing, cost-effective and environment-friendly HCCs as a predominant candidate for ultralight carbon-based EMW absorbing materials.
引用
收藏
页码:101 / 111
页数:11
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