Advances in direct production of value-added chemicals via syngas conversion

被引：71

作者：

An, Yunlei ^{[1
,2
]}

Lin, Tiejun ^{[2
]}

Yu, Fei ^{[2
,3
]}

Yang, Yanzhang ^{[2
,3
]}

Zhong, Liangshu ^{[2
]}

Wu, Minghong

Sun, Yuhan ^{[2
,4
]}

机构：

[1] Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China

[2] Chinese Acad Sci, CAS Key Lab Low Carbon Convers Sci & Engn, Shanghai Adv Res Inst, Shanghai 201203, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[4] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201203, Peoples R China

来源：

SCIENCE CHINA-CHEMISTRY | 2017年 / 60卷 / 07期

基金：

中国国家自然科学基金;

关键词：

green carbon science; syngas conversion; Fischer-Tropsh; Fischer-Tropsh to olefins; higher alcohol synthesis; FISCHER-TROPSCH SYNTHESIS; HIGHER ALCOHOL SYNTHESIS; SUPPORTED IRON CATALYSTS; MODIFIED CU/ZNO/AL2O3 CATALYSTS; CARBON-MONOXIDE HYDROGENATION; CUFE BIMETALLIC NANOPARTICLES; PROMOTED CO/AC CATALYSTS; SYNTHESIS GAS CONVERSION; LINEAR ALPHA-ALCOHOLS; CO-BASED CATALYSTS;

D O I：

10.1007/s11426-016-0464-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Syngas conversion to fuels and chemicals is one of the most challenging subjects in the field of C1 chemistry. It is considered as an attractive alternative non-petroleum-based production route. The direct synthesis of olefins and alcohols as high value-added chemicals from syngas has drawn particular attention due to its process simplicity, low energy consumption and clean utilization of carbon resource, which conforms to the principles of green carbon science. This review describes the recent advances for the direct production of lower olefins and higher alcohols via syngas conversion. Recent progress in the development of new catalyst systems for enhanced catalytic performance is highlighted. We also give recommendations regarding major challenges for further research in syngas conversion to various chemicals.

引用

页码：887 / 903

页数：17

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