Supramolecular Organization in Tetra Aqua (μ-8-Hydroxyquinoline-5-sulfonate) Barium (II) and Ag•••I Interactions in a Pseudopolymorphic Form of (7-Iodo-8-hydroxyquinoline-5-sulfonate) Silver (I) Monohydrate

被引：6

作者：

Balasubramani, K. ^{[1
]}

Hemamalini, M. ^{[1
]}

Francis, S. ^{[1
]}

Muthiah, P. Thomas ^{[1
]}

Vijay, T. ^{[2
]}

Row, T. N. Guru ^{[2
]}

Bocelli, G. ^{[3
]}

Cantoni, A. ^{[3
]}

机构：

[1] Bharathidasan Univ, Sch Chem, Tiruchirappalli 620024, India

[2] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India

[3] IMEM CNR, I-43010 Fontanini Parma, Italy

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2010年 / 40卷 / 04期

关键词：

Metal sulfoxinates; Supramolecular chemistry; Pseudopolymorphism; X-ray diffraction analysis; IR spectra; Electronic spectra; CRYSTAL-STRUCTURE; COORDINATION MODES; HYDROGEN; INTERCALATION; CHEMISTRY; COMPLEX; EXFOLIATION; INTERPLAY; BASE;

D O I：

10.1007/s10870-009-9653-6

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The complexes, Ba (HQS) (H2O)(4) (HQS = 8-hydroxyquinoline-5-sulfonic acid) (1) and Ag (HIQS) (H2O) (Ferron = 7-iodo-8-hydroxyquinoline-5-sulfonic acid) (2) have been synthesized and characterized by X-ray diffraction analysis and spectroscopic studies. In compound 1, Ba2+ ion has a nine-coordinate monocapped antiprismatic geometry. In compound 2, Ag+ has distorted tetrahedral coordination and Ag center dot center dot center dot I interactions generate the supramolecular architectures. The complexes have been characterized by FT-IR and UV-Visible measurements. In both the structures, the inversion-related organic ligands are stacked over one another leading to three-dimensional networks.

引用

页码：316 / 322

页数：7

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