Stereoselective synthesis of cis-1-aryl-2-benzoyl-3,3-dicyanocyclopropanes in the presence of KF•2H2O

被引：28

作者：

Ren, ZJ ^{[1
]}

Cao, WG

Ding, WY

Wang, Y

Wang, LL

机构：

[1] Shanghai Univ, Dept Chem, Shanghai 200436, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2004年 / 34卷 / 20期

基金：

中国国家自然科学基金;

关键词：

arsonium ylide; cis-cyclopropane; cyclopropanation; potassium fluoride dihydrate; stereoselective synthesis;

D O I：

10.1081/SCC-200032500

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

KF (.) 2H(2)O was found to be a highly efficient base for synthesis of cis-1,2-cyclopropanes with arsonium salt and olefins. The advantages of the process are mild reaction condition, easy workup, excellent yields, and high stereoselectivity.

引用

页码：3785 / 3792

页数：8

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