Novel layered organic-inorganic networks assembled from PbI2 and N,N′-bis(3-pyridylmethyl)-1,4-biphenylenedimethyleneimine

被引：14

作者：

Kong, LY

Zhang, ZH

Okamura, TA

Fei, MJ

Sun, WY ^{[1
]}

Ueyama, N

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Toyonaka, Osaka 5600043, Japan

[3] Nanjing Univ, Sch Life Sci, State Key Lab Pharmaceut Biotechnol, Nanjing 210093, Peoples R China

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 12期

关键词：

D O I：

10.1246/cl.2004.1572

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel metal-organic frameworks with different structures were obtained by reactions of Pbl(2) with N,N'-bis(3-pyridylmethyl)-1,4-biphenylenedimethyleneimine (L) under different M/L ratios. When the M/L ratio is 1:1, L bridges [Pbl(2)](n) chains to form a layered organic-inorganic hybrid compound with the empirical formula [Pb(L)I-2] (1). When changing the M/L ratio to 2:1, L bridges the double chains [Pb-2(L)I-4](n) to form networks [Pb-2(L)I-4] (2), which are further linked by C-(HI)-I-... hydrogen bonds to give a 3D structure.

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页码：1572 / 1573

页数：2

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