Formation and structure of novel ternary complexes of thallium(III)cyanide-amine (ethylenediamine and triethylenetetramine) in solution and in solid

被引：4
作者：
Ma, GB [2 ]
Fischer, A
Ilyukhin, A
Glaser, J
机构：
[1] Shanxi Univ, Dept Chem, Taiyuan 030006, Peoples R China
[2] Royal Inst Technol, KTH, Dept Chem, S-10044 Stockholm, Sweden
来源：
INORGANICA CHIMICA ACTA | 2003年 / 344卷
关键词：
thallium; cyano bridge; ethylenediamine; triethylenetetramine; multinuclear NMR; ternary complexes;
D O I：
10.1016/S0020-1693(02)01315-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel ternary Tl(III) complex [Tl(en)(2)(CN)](2+) has been synthesized and characterized in solution by NMR and in solid by Raman spectroscopy. This complex has been prepared in the solid state, [Tl(en)(2)(CN)](ClO4)(2) (1), and the related [Tl(tren)(CN)(2)](ClO4) (2), and their crystal structures determined by X-ray diffraction. A linear cyano-bridged supramolecular complex exists in [Tl(en)(2)(CN)](ClO4)(2). In [Tl(tren)(CN)(2)](ClO4), the thallium ion exists in a distorted octahedral geometry cis coordinated cyanides. (C) 2002 Elsevier Science B.V. All rights reserved.
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收藏
页码：117 / 122
页数：6
相关论文
共 33 条
  • [1] ACETONITRILE AND CYANIDE COMPOUNDS CONTAINING METAL-METAL BONDS - SYNTHESES, STRUCTURES AND APPLICATIONS TO SOLID-STATE CHEMISTRY
    BARTLEY, SL
    BERNSTEIN, SN
    DUNBAR, KR
    [J]. INORGANICA CHIMICA ACTA, 1993, 213 (1-2) : 213 - 231
  • [2] Complex formation in the ternary system Tl(III)-CN--Cl- in aqueous solution. A Tl-205 NMR study
    Berg, KE
    Blixt, J
    Glaser, J
    [J]. INORGANIC CHEMISTRY, 1996, 35 (24) : 7074 - 7081
  • [3] BIEDERMANN G, 1953, ARK KEMI, V5, P441
  • [4] STRUCTURE OF THALLIUM(III) CHLORIDE, BROMIDE, AND CYANIDE COMPLEXES IN AQUEOUS-SOLUTION
    BLIXT, J
    GLASER, J
    MINK, J
    PERSSON, I
    PERSSON, P
    SANDSTROM, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (18) : 5089 - 5104
  • [5] DETERMINATION OF STABILITY-CONSTANTS FOR THALLIUM(III) CYANIDE COMPLEXES IN AQUEOUS-SOLUTION BY MEANS OF C-13 AND TL-205 NMR
    BLIXT, J
    GYORI, B
    GLASER, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (20) : 7784 - 7791
  • [6] EQUILIBRIA AND DYNAMICS OF TL(EDTA)X2- COMPLEXES (X = HALIDE, PSEUDOHALIDE) STUDIED BY MULTINUCLEAR NMR
    BLIXT, J
    GLASER, J
    SOLYMOSI, P
    TOTH, I
    [J]. INORGANIC CHEMISTRY, 1992, 31 (25) : 5288 - 5297
  • [7] DAMUDE LC, 1979, J ORGANOMET CHEM, V168, P123, DOI 10.1016/S0022-328X(00)92000-X
  • [8] DREW MGB, 1970, INORG NUCL CHEM LETT, V6, P163
  • [9] ON THE CRYSTAL-STRUCTURE OF THE TETRABUTYLAMMONIUM TETRAIODOTHALLATE(III) [N(C4H9)4][TLI4]
    GLASER, J
    GOGGIN, PL
    SANDSTROM, M
    LUTSKO, V
    [J]. ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1983, 37 (05): : 437 - 445
  • [10] CRYSTAL-STRUCTURES OF THE ISOMORPHOUS PERCHLORATE HEXAHYDRATES OF SOME TRIVALENT METAL-IONS (M=LA, TB, ER, TL)
    GLASER, J
    JOHANSSON, G
    [J]. ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1981, 35 (09): : 639 - 644
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