Pure vibrational dephasing of triiodide in liquids and glasses

被引：1

作者：

Zhang, FS ^{[1
]}

Lynden-Bell, RM ^{[1
]}

机构：

[1] Queens Univ Belfast, Sch Math & Phys, Atomist Simulat Grp, Belfast BT7 1NN, Antrim, North Ireland

来源：

MODERN PHYSICS LETTERS A | 2003年 / 18卷 / 2-6期

关键词：

D O I：

10.1142/S0217732303010570

中图分类号：

P1 [天文学];

学科分类号：

0704 ;

摘要：

A molecular dynamics model is developed to investigate the pure vibrational dephasing of 1 3 in solvent at temperatures ranging from room temperature to 100 K. The triiodide ion is described by a valence bond model which responds to the field of the classical solvent molecules. We find that the pure dephasing rate does not change much with temperature. This result can then be interpreted in terms of of Kubo lineshape theory.

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页码：406 / 409

页数：4

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