Metal-organic framework derived Au@ZnO yolk-shell nanostructures and their highly sensitive detection of acetone

被引:27
|
作者
Gu, Fubo [1 ]
Chen, Huanhuan [1 ]
Han, Dongmei [1 ]
Wang, Zhihua [1 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
FLOWER-LIKE; FACILE SYNTHESIS; SENSING PERFORMANCE; NANOPARTICLES; CARBON; OXIDE; NANOCRYSTALS; DEGRADATION; NANOSPHERES; ALPHA-FE2O3;
D O I
10.1039/c6ra03034c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Au@ZnO yolk-shell nanostructures were synthesized by using Au@MOF-5 as a precursor. The morphological and structural properties of the products were characterized by XRD, SEM, TEM, TGA, XPS and UV-vis DRS. The morphology of the products could be tuned by the synthesis and calcination conditions. The acetone-sensing performance of the Au@ZnO yolk-shell nanostructures was investigated. The sensor based on Au@ZnO exhibited a high response (43 to 10 ppm acetone), low detection concentration of 50 ppb, excellent selectivity and short response/recovery time (15 s/12 s). The as-synthesized Au@ZnO has a promising application in acetone detection.
引用
收藏
页码:29727 / 29733
页数:7
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