The Leaf Essential Oils of Juniperus communis L. Varieties in North America and the NMR and MS Data for Isoabienol

被引:19
作者
Adams, Robert P. [1 ]
Beauchamp, P. S. [2 ]
Dev, Vasu [2 ]
Bathala, Radha M. [2 ]
机构
[1] Baylor Univ, Dept Biol, Gruver, TX 79040 USA
[2] Calif State Polytech Univ Pomona, Dept Chem, Pomona, CA 91768 USA
关键词
Juniperus communis var. charlottensis; Juniperus communis var. depressa; Juniperus communis var. jackii; Juniperus communis var. megistocarpa; Juniperus communis var. saxatilis; Cupressaceae; essential oil composition; alpha-pinene; delta-3-carene; beta-phellandrene; isoabienol; POLYMORPHIC DNAS RAPDS; LIVERWORT JUNGERMANNIA-INFUSCA; WESTERN-HEMISPHERE; SYSTEMATICS; DITERPENOIDS; MADEIRA; BERTH;
D O I
10.1080/10412905.2010.9700258
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This is first report oil the composition of the leaf essential oils of J. communis L varieties front the Western Hemisphere. The oil of Juniperus communis var. jackii had the most distinct oil and contained moderate amounts of alpha-pinene (16.1-18.9%), delta-3-carene (17.9-28.4%) and beta-phellandrene (9.2-13.4%) along with several diterpenes including isoabienol. Juniperus communis var. charlottensis oil had a very high concentration of alpha-pinene (59.3%), with moderate amounts of beta-pinene (5.9%), delta-3-carene (3.6%) and beta-phellandrene (2.9%). The oil of J. communis var. depressa was dominated by alpha-pinene (53.9%), delta-3-carene (9.3%) and beta-pinene (5.5%) and was a little unusual in also containing citronellol, citronellyl acetate, neryl acetate and geranyl acetate with no diterpenes. The oil of J. communis var. megistocarpa possessed large amounts of alpha-pinene (58.5%), limonene (20.4%) and beta-pinene (5.0%) and, like J. communis var. depressa, its oil also contained citronellol, citronellyl acetate, neryl acetate and geranyl acetate. Putative J. communis var. saxatilis from Idaho, USA, had a high concentration of alpha-pinene (56.5%) with moderate amounts of delta-3-carene (11.5%), beta-pinene (5.4%), myrcene (4.5%) and beta-phellandrene (3.1%). The oils of these North American varieties were compared to J. communis var. communis (Sweden) and J. communis var. saxatilis (Switzerland). A survey of approximately 65 species of Juniperus revealed that isoabienol was present in eight species. X-ray, MS and (13)C-NMR were used to determine the structure of isoabienol (I) and KI and a mass spectrum is presented to aid future identification.
引用
收藏
页码:23 / 28
页数:6
相关论文
共 16 条
[1]  
Adams R.P., 2014, Junipers of the world: the genus Juniperus
[2]  
Adams R.P., 2007, PHYTOLOGIA, V89, P43
[3]  
Adams R.P., 1991, MODERN METHODS PLANT, V12, P159
[4]  
Adams R.P, 2006, IDENTIFICATION ESSEN, V4th
[5]  
Adams R. P., 2008, PHYTOLOGIA, V90, P176
[6]   The serrate leaf margined Juniperus (Section Sabina) of the western hemisphere:: systematics and evolution based on leaf essential oils and Random Amplified Polymorphic DNAs (RAPDs) [J].
Adams, RP .
BIOCHEMICAL SYSTEMATICS AND ECOLOGY, 2000, 28 (10) :975-989
[7]   Systematics of multi-seeded eastern hemisphere Juniperus based on leaf essential oils and RAPD DNA fingerprinting [J].
Adams, RP .
BIOCHEMICAL SYSTEMATICS AND ECOLOGY, 1999, 27 (07) :709-725
[8]   Systematics of the one seeded Juniperus of the eastern hemisphere based on leaf essential oils and random amplified polymorphic DNAs (RAPDs) [J].
Adams, RP .
BIOCHEMICAL SYSTEMATICS AND ECOLOGY, 2000, 28 (06) :529-543
[9]   Systematics of Juniperus section Juniperus based on leaf essential oils and random amplified polymorphic DNAs (RAPDs) [J].
Adams, RP .
BIOCHEMICAL SYSTEMATICS AND ECOLOGY, 2000, 28 (06) :515-528
[10]   Systematics of smooth leaf margin Juniperus of the western hemisphere based on leaf essential oils and RAPD DNA fingerprinting [J].
Adams, RP .
BIOCHEMICAL SYSTEMATICS AND ECOLOGY, 2000, 28 (02) :149-162