Crystal and magnetic structures of the Bi1-x Sr x FeO3-δ and Bi1-x A x Fe1-x Mn x O3 (A = Sr, Ca) solid solutions

被引：5
|
作者：
Troyanchuk, I. O. [1 ]
Karpinskii, D. V. [1 ]
Bushinskii, M. V. [1 ]
Chobot, A. N. [1 ]
Pushkarev, N. V. [1 ]
Prohnenko, O. [2 ]
Kopcewicz, M. [3 ]
Szymczak, R. [4 ]
机构：
[1] Natl Acad Sci Belarus, Joint Inst Solid State & Semicond Phys, Minsk 220072, BELARUS
[2] Helmholtz Zentrum Berlin Mat & Energie GmbH, D-14109 Berlin, Germany
[3] Inst Elect Mat Technol, PL-01919 Warsaw, Poland
[4] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland
来源：
CRYSTALLOGRAPHY REPORTS | 2009年 / 54卷 / 07期
关键词：
Neutron Diffraction; Magnetic Structure; Crystallography Report; Hyperfine Field; Neutron Diffraction Data;
D O I：
10.1134/S1063774509070074
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Bi1 - x Sr (x) FeO3 - x/2 (I), Bi1 - x Sr (x) Fe1 - x MnxO(3) (II), and Bi1 - x Ca (x) Fe1 - x Mn (x) O-3 (III) solid solutions have been obtained. Their magnetization has been measured by X-ray and neutron diffraction and Mossbauer spectroscopy. According to the Mossbauer spectroscopy data, iron ions are in the trivalent state in system I. Near the concentration x a parts per thousand 0.2, rhombohedral distortions (sp. gr. R3c) are transformed into tetragonal (P4/mmm). The symmetry of system II changes at x > 0.2 (R3c -> R3c), whereas orthorhombic distortions (R3c -> Pbnm) arise in system III at x > 0.2. The magnetic structure is antiferromagnetic (of G type). The samples of systems II and III exhibit weak ferromagnetism at x > 0.2 due to the Dzyaloshinski-Moriya interaction.
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收藏
页码：1172 / 1178
页数：7
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