Synthesis of 1,2-diketones by mercury-catalyzed alkyne oxidation

被引：2

作者：

Mei, Xiaochuan ^{[1
]}

Hu, Weican ^{[1
]}

Gao, Kexin ^{[1
]}

Gao, Haotian ^{[1
]}

Wang, Chaoyang ^{[1
]}

Qian, Guoying ^{[1
]}

Rong, Zhouting ^{[1
]}

机构：

[1] Zhejiang Wanli Univ, Coll Biol & Environm Sci, Ningbo, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2021年 / 51卷 / 17期

关键词：

Alkyne oxidation; 1; 2-diketones; Mercury catalysis; ONE-POT SYNTHESIS; ALPHA-KETOAMIDES; BENZIL DERIVATIVES; MOLECULAR-OXYGEN; BOND-CLEAVAGE; METAL-FREE; DIARYLALKYNES; INHIBITION; ENAMINONES; DIKETONES;

D O I：

10.1080/00397911.2021.1946082

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first mercury-catalyzed synthesis of 1,2-diketones by alkyne oxidation has been developed. This inexpensive method extends the potential of mercury catalysis and allows the rapid construction of various 1,2-diketones and alpha-carbonyl amides in good yields with high functional group tolerance.

引用

页码：2661 / 2667

页数：7

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