(4-Carboxy-2-sulfonatobenzoato-κ2O1,O2)bis(1,10-phenanthroline-κ2N,N′)manganese(II)

被引：0
|
作者：
Wu, Qiong-Fang [1 ]
Li, Ming-Xing [1 ]
机构：
[1] Shanghai Univ, Coll Sci, Dept Chem, Shanghai 200444, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2010年 / 66卷
关键词：
D O I：
10.1107/S1600536810023743
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [Mn(C8H4O7S)(C 12H8N2)2], the MnII atom is chelated by one 4-carboxy-2-sulfonato-benzoate anion and two phenathroline (phen) ligands in a distorted octa-hedral MnN4O2 geometry. The benzene ring of the 4-carboxy-2-sulfonato-benzoate anion is twisted with respect to the two phen ring systems at dihedral angles of 66.38 (9) and 53.56 (9)°. In the crystal, inter-molecular O-H⋯O and C-H⋯O hydrogen bonding links the molecules into chains running parallel to [100]. Inter-molecular π-π stacking is also observed between parallel phen ring systems, the face-to-face distance being 3.432 (6) Å.
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页码：M849 / U1262
页数：14
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