Polymers in dye sensitized solar cells: overview and perspectives

被引：409

作者：

Nogueira, AF ^{[1
]}

Longo, C ^{[1
]}

De Paoli, MA ^{[1
]}

机构：

[1] Inst Quim, Lab Polimeros Condutores & Reciclagem, BR-13084971 Campinas, SP, Brazil

来源：

COORDINATION CHEMISTRY REVIEWS | 2004年 / 248卷 / 13-14期

基金：

巴西圣保罗研究基金会;

关键词：

solid-state dye sensitized cell; polymer electrolytes; polymer electrodes; conducting polymers;

D O I：

10.1016/j.ccr.2004.05.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dye sensitized solar cells (DSSC) are the result of a combination Of several different materials: optically transparent electrodes, nanoparticulated semiconductors, coordination compounds, inorganic salts, solvents and metallic catalysts. Each material performs a specific task toward the overall objective of harvesting solar light and transforming it into electricity. To improve the efficiency and increase the technological perspectives of DSSC, there is a tendency to substitute some of these materials by polymers. Poly(ethylene terephthalate) based electrodes can substitute glass electrodes, improving the flexibility and impact resistance of a DSSC. Liquid electrolytes are volatile and may leak if the cell is not properly sealed. Their replacement by polymeric electrolytes solves both problems with the additional advantage that they act as a binder for the electrodes. More recently, intrinsically conducting polymers have been used as hole conducting materials in DSSC, with promising results. In this review we will discuss these tendencies, highlighting the advantages of using polymers, and discussing the problems faced by researchers working in this area. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1455 / 1468

页数：14

共 119 条

[11]

ARMAND MB, 1987, POLYM ELECTROLYTE RE, V1

[12] Charge separation in solid-state dye-sensitized heterojunction solar cells [J].

Bach, U ;

Tachibana, Y ;

Moser, JE ;

Haque, SA ;

Durrant, JR ;

Grätzel, M ;

Klug, DR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (32) :7445-7446

[13]

BALASUBARAMANIA.S, 2001, PHOTOVOLTAIC CELLS

[14]

BARBEC CJ, 1999, SYNTHETIC MET, V102, P8611

[15] Optimization of dye-sensitized solar cells prepared by compression method [J].

Boschloo, G ;

Lindström, J ;

Magnusson, E ;

Holmberg, A ;

Hagfeldt, A .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 148 (1-3) :11-15

[16] A SOLID-STATE, DYE-SENSITIZED PHOTOELECTROCHEMICAL CELL [J].

CAO, F ;

OSKAM, G ;

SEARSON, PC .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (47) :17071-17073

[17]

COWIE M, 1987, POLYM ELECTROLYTE RE, V1

[18] Nanocomposite polymer electrolytes for lithium batteries [J].

Croce, F ;

Appetecchi, GB ;

Persi, L ;

Scrosati, B .

NATURE, 1998, 394 (6692) :456-458

[19] Photoelectrochemical characterization of electrodeposited polyaniline [J].

dasNeves, S ;

daFonseca, CNP ;

DePaoli, MA .

SYNTHETIC METALS, 1997, 89 (03) :167-169

[20] Photogeneration and transport of charge carriers in hybrid materials of conjugated polymers and dye-sensitized TiO2 [J].

Däubler, TK ;

Glowacki, I ;

Scherf, U ;

Ulanski, J ;

Hörhold, HH ;

Neher, D .

JOURNAL OF APPLIED PHYSICS, 1999, 86 (12) :6915-6923

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