Hydrolytic synthesis and structural characterization of five hexanuclear oxo-hydroxo lanthanide clusters

被引：23

作者：

Tong, Yu-Zhang ^{[1
]}

Wang, Qing-Lun ^{[1
]}

Yang, Guang ^{[1
]}

Yang, Guang-Ming ^{[1
]}

Yan, Shi-Ping ^{[1
]}

Liao, Dai-Zheng ^{[2
]}

Cheng, Peng ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

[2] Nankai Univ, Key Lab Met & Mol Mat Chem Tianjin City, Tianjin 300071, Peoples R China

来源：

CRYSTENGCOMM | 2010年 / 12卷 / 02期

基金：

中国国家自然科学基金;

关键词：

EARTH BASIC NITRATES; CRYSTAL-STRUCTURES; COMPLEXES; GD; TB; LN; CHEMISTRY; CATALYSIS; IODIDE; EU;

D O I：

10.1039/b914208h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Five hexanuclear oxo-hydroxo lanthanide clusters are synthesized by hydrolysis of the lanthanide ions together with 4-amido-3,5-dimethyl-1,2,4-triazole (L). They all have a [Ln(6)(mu(6)-O)(mu(3)-OH)(8)](8+) core structure and the triazole groups stabilize the core structure in different fashions. The oxo group functions as an anion template to induce the self-assembly of lanthanide ions.

引用

页码：543 / 548

页数：6

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