Multi-Gram Scale Synthesis of 1,2,3-Triazolium Ionic Liquids and Assay of Their Resistance towards Bases

被引：11
作者：
Raiguel, Stijn [1 ]
Thomas, Joice [1 ]
Binnemans, Koen [1 ]
Dehaen, Wim [1 ]
机构：
[1] Katholieke Univ Leuven, Dept Chem, Celestijnenlaan 200F POB 2404, B-3001 Leuven, Belgium
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 2018卷 / 35期
关键词：
Ionic liquids; Green chemistry; Grignard reaction; Triazolium salts; SOLVENT-EXTRACTION; SALTS; CYCLOADDITION; STABILITY; DATABASE; CATIONS; AZIDES;
D O I：
10.1002/ejoc.201800925
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An easily upscalable synthesis method for 1,2,3-triazolium ionic liquids is presented. Several ionic liquids were synthesized and characterized. The influence of the side chain structure on the base-stability was investigated. One example, functionalized with linear alkyl side chains, was found to exhibit excellent stability against hot concentrated NaOH solutions and Grignard reagents.
引用
收藏
页码：4850 / 4856
页数：7
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