One-step nanocasting synthesis of highly ordered single crystalline indium oxide nanowire arrays from mesostructured frameworks

被引：212

作者：

Yang, HF ^{[1
]}

Shi, QH ^{[1
]}

Tian, BZ ^{[1
]}

Lu, QY ^{[1
]}

Gao, F ^{[1
]}

Xie, SH ^{[1
]}

Fan, J ^{[1
]}

Yu, CZ ^{[1
]}

Tu, B ^{[1
]}

Zhao, DY ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 16期

关键词：

D O I：

10.1021/ja034005i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A one-step nanocasting route has been demonstrated to prepare highly ordered single-crystal indium oxide nanowire (IONW) arrays with mesostructured frameworks. Unlike the reported multistep nanocasting process (synthesis of mesoporous materials, and then incorporation of precursors and formation of inorganic frameworks), a highly ordered mesostructured surfactant-silica monolith with low external surface serves as both the template and the reducing agent and makes the formation of single-crystal IONWs in its channels easily in one step by using normal In(NO3)3 as an inorganic precursor. After silica is removed, highly ordered uniform single-crystal IONW arrays with hexagonal (p6mm) or cubic (Ia3d) mesostructures are derived. These new materials are studied by XRD, SEM, TEM, N2 adsoption, and UV spectrum. Furthermore, this one-step nanocasting synthesis route is a generalized method and can be used to synthesized a highly ordered mesoporous silica monolith with metal oxide nanocrystals in its channels. To the best of our knowledge, this is the first report of a single crystalline mesostructured In2O3 framework. Copyright © 2003 American Chemical Society.

引用

页码：4724 / 4725

页数：2

共 20 条

[1] The preparation of transparent electrically conducting indium oxide films by reactive vacuum evaporation [J].

Gopchandran, KG ;

Joseph, B ;

Abraham, JT ;

Koshy, P ;

Vaidyan, VK .

VACUUM, 1997, 48 (06) :547-550

[2] Criteria for choosing transparent conductors [J].

Gordon, RG .

MRS BULLETIN, 2000, 25 (08) :52-57

[3] Grain size control in nanocrystalline In2O3 semiconductor gas sensors [J].

Gurlo, A ;

Ivanovskaya, M ;

Barsan, N ;

Schweizer-Berberich, M ;

Weimar, U ;

Gopel, W ;

Dieguez, A .

SENSORS AND ACTUATORS B-CHEMICAL, 1997, 44 (1-3) :327-333

[4] Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles [J].

Joo, SH ;

Choi, SJ ;

Oh, I ;

Kwak, J ;

Liu, Z ;

Terasaki, O ;

Ryoo, R .

NATURE, 2001, 412 (6843) :169-172

[5] Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure [J].

Jun, S ;

Joo, SH ;

Ryoo, R ;

Kruk, M ;

Jaroniec, M ;

Liu, Z ;

Ohsuna, T ;

Terasaki, O .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (43) :10712-10713

[6] Structural study of mesoporous MCM-48 and carbon networks synthesized in the spaces of MCM-48 by electron crystallography [J].

Kaneda, M ;

Tsubakiyama, T ;

Carlsson, A ;

Sakamoto, Y ;

Ohsuna, T ;

Terasaki, O ;

Joo, SH ;

Ryoo, R .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (06) :1256-1266

[7] Synthesis of porous palladium superlattice nanoballs and nanowires [J].

Kang, H ;

Jun, Y ;

Park, JI ;

Lee, KB ;

Cheon, J .

CHEMISTRY OF MATERIALS, 2000, 12 (12) :3530-+

[8]

Liang CH, 2001, ADV MATER, V13, P1330, DOI 10.1002/1521-4095(200109)13:17<1330::AID-ADMA1330>3.0.CO

[9]

2-6

[10] Synthesis and characterization of indium oxide nanoparticles [J].

Murali, A ;

Barve, A ;

Leppert, VJ ;

Risbud, SH ;

Kennedy, IM ;

Lee, HWH .

NANO LETTERS, 2001, 1 (06) :287-289

← 1 2 →