Structural characterization of crystalline inclusion complexes formed from 1,3,5-triaroylbenzene derivatives - a new family of inclusion hosts

被引：27
|
作者：
Pigge, FC [1 ]
Ghasedi, F [1 ]
Zheng, ZM [1 ]
Rath, NP [1 ]
Nichols, G [1 ]
Chickos, JS [1 ]
机构：
[1] Univ Missouri, Dept Chem, St Louis, MO 63121 USA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 2000年 / 12期
关键词：
D O I：
10.1039/b005702i
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of crystalline inclusion complexes formed from substituted 1,3,5-triaroylbenzene hosts and small molecule guests has been structurally characterized by X-ray crystallography. The new inclusion hosts examined do not possess functional groups capable of participating in strong non-covalent interactions, thus C-H . . .O hydrogen bonding appears to significantly influence the crystal packing observed in most of the solid state structures. The thermochemical properties of the inclusion complexes were examined using differential scanning calorimetry.
引用
收藏
页码：2458 / 2464
页数：7
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