Studies on sodium trifluoromethanesulfonate. Crystal structure of sodium trifluoromethanesulfonate-trifluoromethanesulfonic acid (1/3)

被引：4
作者：
Korus, G [1 ]
Jansen, M [1 ]
机构：
[1] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1998年 / 53卷 / 04期
关键词：
sodium trifluoromethanesulfonate; sodium triflate; trifluoromethanesulfonic acid; synthesis; crystal structure;
D O I：
10.1515/znb-1998-0409
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Single crystals of sodium trifluoromethanesulfonate-trifluoromethanesulfonic acid (1/3) (NaSO3CF3 . 3 HSO3CF3) have been prepared by reaction of sodium trifluoromethanesulfonate with anhydrous trifluoromethanesulfonic acid at 60 degrees C. NaSO3CF3 . 3 HSO3CF3 crystallizes in space group I2(1)3 (No. 199) with a = 16.210(1) Angstrom. Z = 8. Sodium is coordinated by six oxygen atoms from six different trifluoromethanesulfonic acid molecules, each acid molecule connecting two sodium ions. The 3-dimensional network resulting from the edge sharing octahedra corresponds to the cubic (10, 3) net, not realised otherwise, so far. The trifluoromethanesulfonnte anion is bonded to three trifluoromethanesulfonic acid molecules by hydrogen bonds.
引用
收藏
页码：438 / 442
页数：5
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